A unique, high surface area Co3O4/SiO2–Al2O3 catalytic system has been developed for the selective deoxygenation of biomass to high quality diesel-grade hydrocarbons.
A series of palladium nanoparticles (Pd NPs) intercalated montmorillonite clay catalysts is reported for hydrogenation of 3-diphenyl prop-2-en-1-imine under mild reaction conditions. Pd/clay catalyst was prepared by a simple wet-impregnation method, and the physicochemical properties were characterized extensively by various techniques including N 2 adsorption, XRD, TEM, XPS and TPR etc., which showed the intercalation of active Pd NPs between the clay layers. The effect of reaction conditions such as catalyst loading, reaction time, temperature and H 2 pressure is explored, and thereby a plausible mechanism is proposed. The optimum amount of 6 wt % Pd/clay catalyst showed significant catalytic activity to yield 3-phenyl propyl aniline with 100 % conversion and selectivity under 5 bar pressure and a shorter reaction period of 3.5 h at 100°C. The developed catalytic system unveiled excellent reusability over five cycles and hence paved the way for industrial applications.
Nanometer and subnanometer particles and films are becoming an essential and integral part of new technologies and inventions in different areas. Some of the most common areas include the microelectronic industry, magnetic recordings, photovoltaic applications, and optical coatings. Because of the ultrasmall size at atomic levels, the effect of quantum size becomes prominent, and the sensitivity of size is defined even by a difference of a single atom. Additionally, the effect is of utmost importance as the single-atom catalysts are far more advantageous than conventional catalysts as they tend to anchor easily because of their low coordination. Also, the presence of a single-atom catalyst in reactions creates efficient charge transfer as it forms a strong interaction with the support. Furthermore, catalysts in the subnanometer regime exhibit different electronic states and adsorption capabilities compared to traditional catalysts. Therefore, to fully appreciate the subnanometer catalysis reactions, it is essential to study the means of characterizing the prepared subnano catalysts, in order to characterize the materials in their as-synthesized form, to obtain a precise and accurate analysis; these are some of the fundamental requirements for achieving an optimum performance. The physical properties of many interesting materials for advanced technological usage are highly governed by the distribution and placement of atoms. Superior techniques such as high-resolution transmission electron microscopy and high-angle annular dark-field scanning transmission electron microscopy and infrared and X-ray absorption spectroscopic techniques provide electronic and geometric configurations and also reveal the transformation of the subnano catalysts on the support material. Modeling methods such as density functional theory can successfully predict the electronic structure and geometric configuration of the catalyst, which in turn influence the selectivity and activity of the catalyst. Thus, understanding the characterization techniques gives the ability to understand, identify, and measure the local environment of individual atoms and the interaction with the surface support, which will give fundamental knowledge and insights in the realms of nanoscience and technology, materials science, chemistry, and physics. Therefore, detection and enhanced measurement
Soot particulates in engine exhaust pose a severe threat to the environment and human health - causing cancer, affecting the heart, lung and drives mental processes. This study proposes a...
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