Abbreviations: AA ,ascorbic acid; BHT, butylated hydroxy toluene; DPPH, 2, 2-diphenyl-1-picrylhydrazyl; SEM, scanning electron microscopy; S/G, starch/glycerol; S/G/AA, starch/glycerol/ascorbic acid; S/G/BHT, starch/glycerol/butylated hydroxy toluene; Tg, glass transition temperature; WVP, water vapour permeability; ΔH, enthalphy of transition.
Keywords: Starch film, WVP, Tensile properties, Thermal analysis, Antioxidant release. †This article has been accepted for publication and undergone full peer review but has not been through the copyediting, typesetting, pagination and proofreading process, which may lead to differences between this version and the Version of Record. Please cite this article as doi: [10.1002/star.201400193]. This article is protected by copyright. All rights reserved. Received: October 2, 2014 / Revised: November 11, 2014 / Accepted: November 11, 2014
AbstractActive antioxidant food packaging films were developed by the incorporation of ascorbic acid (AA) and butylated hydroxy toluene (BHT) into a rice starch-glycerol matrix. BHT significantly improved the water resistance of starch films. Both AA and BHT promoted significant increase in the elastic modulus but a decrease in film stretchability. S/G/BHT film presented significant decrease in water vapour permeability (WVP). AA and BHT significantly affected the lightness (L*) and yellow (b*) color of the films with minor differences in the green (a*) color. SEM revealed smooth surface of the films. Thermal analysis showed increase in glass transition temperature (Tg) and enthalphy of transition (ΔH) of films with the incorporation of AA and BHT. Exposure of the films to various food simulants showed that the release from the films was dependent on the type of food simulant and the antioxidant. In the aqueous food simulant, films containing ascorbic acid (S/G/AA) produced the largest release and in the fatty food stimulant S/G/BHT film presented fast release.
IntroductionDue to the severe environmental pollution caused by plastic food packaging, there has been a growing amount of interest in the production of edible and biodegradable films [1]. Such films may have the ability of decreasing the amounts of non-renewable conventional synthetic polymer packaging materials, and use ingredients of agricultural derived products [2]. Edible films can be prepared from protein, polysaccharides, lipids or the combination of these components [3,4]. Starch is the natural polysaccharide and it is described as a renewable resource, inexpensive and widely available [5]. Starch-based films exhibit appropriate physical characteristics, since these films are isotropic, odourless, non-toxic, biodegradable, tasteless, colourless and constitute a good barrier against oxygen transfer [1]. However starch films are brittle and addition of certain components like glycerol improves their handling properties. Glycerol imparts flexibility and is a widely used plasticizer for making starch-based films and coatings [6,7]. These films may operate as carriers of many...