The structures of medium sized tin cluster anions Sn(n)(-) (n = 16-29) were determined by a combination of density functional theory, trapped ion electron diffraction and collision induced dissociation (CID). Mostly prolate structures were found with a structural motif based on only three repeatedly appearing subunit clusters, the Sn(7) pentagonal bipyramid, the Sn(9) tricapped trigonal prism and the Sn(10) bicapped tetragonal antiprism. Sn(16)(-) and Sn(17)(-) are composed of two face connected subunits. In Sn(18)(-)-Sn(20)(-) the subunits form cluster dimers. For Sn(21)(-)-Sn(23)(-) additional tin atoms are inserted between the building blocks. Sn(24)(-) and Sn(25)(-) are composed of a Sn(9) or Sn(10) connected to a Sn(15) subunit, which closely resembles the ground state of Sn(15)(-). Finally, in the larger clusters Sn(26)(-)-Sn(29)(-) additional bridging atoms again connect the building blocks. The CID experiments reveal fission as the main fragmentation channel for all investigated cluster sizes. This rather unexpected "pearl-chain" cluster growth mode is rationalized by the extraordinary stability of the building blocks.
The structures of bismuth cluster cations in the range between 4 and 14 atoms have been assigned by a combination of gas phase ion mobility and trapped ion electron diffraction measurements together with density functional theory calculations. We find that above 8 atoms the clusters adopt prolate structures with coordination numbers between 3 and 4 and highly directional bonds. These open structures are more like those seen for clusters of semiconducting-in-bulk elements (such as silicon) rather than resembling the compact structures typical for clusters of metallic-in-bulk elements. An accurate description of bismuth clusters at the level of density functional theory, in particular of fragmentation pathways and dissociation energetics, requires taking spin-orbit coupling into account. For n = 11 we infer that low energy isomers can have fragmentation thresholds comparable to their structural interconversion barriers. This gives rise to experimental isomer distributions which are dependent on formation and annealing histories.
We have used both action and photoelectron spectroscopy to study the response of isolated Pd(II) meso-tetra(4-sulfonatophenyl)porphyrin tetraanions ([PdTPPS](4-)) to electronic excitation over the 2.22-2.98 eV photon energy range. The action spectrum obtained by recording the wavelength-dependent intensity of charged decay products closely resembles the absorption spectrum of PdTPPS in aqueous solution (which shows pronounced Q and Soret absorption bands). The two main decay channels observed are sulfonate group loss and, predominantly, electron emission. To better understand the electron emission channel, we have also acquired photoelectron spectra at multiple detachment photon energies covering the range probed in action spectroscopy. Upon both Q and Soret band excitation, we find that electrons are emitted in three characteristic kinetic energy ranges. The corresponding detachment processes are identified as (delayed) tunneling emission from both excited singlet and triplet states (each of which is accessed by/after one-photon absorption) as well as resonant two-photon detachment. The first triplet state lifetime of isolated [PdTPPS](4-) is significantly longer than 10 μs, possibly on the 100 μs time scale. We estimate that more than 50% of the electron emission observed upon photoexcitation occurs by way of this triplet state.
We present structures and photoelectron spectra of Mn(III) and Cu(II) meso-tetra(4-sulfonatophenyl)porphyrin (TPPS) multianions, as well as of homomolecular dimers and trimers thereof. The structural assignments are based on a combination of mass spectrometry, ion mobility measurements, and semiempirical as well as density functional theory (DFT) calculations. Depending on the type of central metal atom, two completely different dimer structural motifs are found. With a central Mn(III), the monomeric units are connected via sulfonic-acid-manganese bonds resulting in a tilted stack arrangement of porphyrin rings. With Cu(II) as the central atom, the sulfonic acid groups preferentially bind to the sodium counterions, resulting in a flat dimer structure with coplanar porphyrins. Photoelectron spectra were recorded for monomers, dimers, and trimers, each in a number of different negative charge states as determined by protonation degree (+nH). In some cases, e.g., [Cu(II)TPPS](4-), [(Mn(III)TPPS)2 + H](5-), and [(Mn(III)TPPS)3 + 3H](6-), we observe electron detachment energies close to zero, or even slightly negative. In all cases, we find a large repulsive Coulomb barrier. The observed trends in detachment energies can be interpreted in terms of a simple electrostatic model.
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