Chemical Kinetics I Complex Compounds I SolutionsBy means of stopped-flow experiments equilibrium and rate constants are determined for the weak complexation of the aluminium(II1)-ion with formate, acetate, chloroacetate and benzoate. For the innersphere complex formation both equilibrium and rate constants depend on the nature of the ligand, and a linear free energy relation is observed between rate constants and dissociation constants of the corresponding acids.
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