The polarized optical absorption and emission (spectra, decay times) of single-crystal [lr(CO)2mnt] TBA at temperatures 2 K^ T<295 K and homogeneous magnetic fields O^H ^ 6T are reported. The highly resolved spectra show 0-0 transitions with vibrational satellites and phonon side bands. Applied magnetic fields yield no effect on the emission. The lowest excited electronic states can be assigned to the spin-orbit components A\, B\, and B\ of the charge transfer triplet 3A2 (symmetry C2l.).
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