Scale formation is one of the major issues in the petroleum industry. The development of these scale layers could result in production losses and equipment instability because of pipeline blockage, energy leakage, corrosion acceleration and severe accidents which will impact the safety of the production process. The utilization of chemical scale inhibitors (SIs) is considered an economical and successful route for the scale prevention. Two main components of the chemical SIs are phosphonate and polymer. Many of the phosphorous compounds are toxic and very expensive. Besides, portions of the phosphonate compounds are thermally less stable than polymeric scale inhibitors in a harsh environment of high temperature and high pressure (HTHP). This is considered as an issue as a good scale inhibitor should be able to be applied under wide range of temperature and pressure. Therefore, the continuous development in petroleum production imposes the need to develop a novel phosphorus-free scale inhibitor. Meanwhile, polymers have been broadly applied as a scale inhibitor in oil and gas fields because of their enhanced thermal stability and improved environmental compatibility. Polymeric scale inhibitors also show better dispersing efficiency. Today, the biopolymers have pulled in a tremendous consideration from the industry to replace the utilization of synthetic polymer due to their interesting qualities such as their lightness, strong mechanical properties, and appealing functionality. Biopolymers are insensitive toward brine salinity yet are vulnerable to biological degradation. Specifically, these polymers present enormous potential for environmental application because of their biodegradability, chemical adaptability and reactivity, biocompatibility, and nontoxicity. Recently, several new eco-friendly scale inhibitors have been reported in the literature. Hence, this paper provides a review of the utilization of biopolymer as scale inhibitor in the application of oil and gas industry under laboratory approach or field trial application. The types of scales, chemical scale inhibitors (SIs) and biopolymers are likewise reviewed here. The presented work in this paper is expected to enhance the fundamental understanding of scale formation, as well as contribute to the development process of biopolymer scale inhibitors.

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Paraffin is a problem commonly faced in petroleum production. The presence of paraffin can inhibit the process of oil flow. Mitigation methods commonly used to overcome this problem is by using chemical injection, which is solvent. In this research, a laboratory experiment was conducted to make bioethanol from agricultural waste that are rice husks and corn cobs. This bioethanol functions as a solvent that is used to reduce the pour point in a waxy-paraffinic crude oil sample. Oil samples were mixed with bioethanol with different mixing ratios, including 5%, 10%, 15%, 20% 50%. The results showed that the alcohol content of the Husk and Corncob rise was 11% and 9% respectively. Then, the best result from mixing of bioethanol with oil reduced the pour point from 43.3 to 41 at mixing ratio of 50%.

The effectiveness of CO2-enhanced oil recovery (EOR) is strongly dependent on the CO2–oil minimum miscible pressure (MMP) value, which can be estimated using various methods. In this study, interfacial tension (IFT) and slim-tube tests were used to estimate the MMP value. Experimental results indicated that the IFT test had a higher MMP value than the slim-tube test. Particularly, the outcomes of IFT and the slim-tube tests differed slightly, i.e., 0.7% and 4.3% at 60 and 66 °C, respectively. Furthermore, the current work also compares MMP data gathered using visual observation and equation of state (EOS) simulation. The MMP estimated by EOS is higher but close to the IFT and slim-tube recovery factor method, where all results are within the 1650–1700 psi and 1700–1800 psi visual observation ranges at 60 and 66 °C, respectively. However, MMP deviations concerning the slim-tube test and EOS were consistent at different temperatures. This study offers an alternative to estimate and evaluate CO2–oil MMP for EOR applications accurately and efficiently.