Flexible supercapacitors have gained significant attention in recent times due to their many advantages such as high specific capacitance, lightweight, long lifespan, high energy density, high flexibility, and high-power density. These benefits make them ideal for various high-power applications in various industries. Copper oxide is particularly attractive as an electrode material because of its high theoretical specific capacitance, low cost, and eco-friendliness. Copper oxide is the most promising electrode material in energy storage systems among metal oxides due to its higher theoretical value of specific capacitance (1800 F/g). In the present study, the synthesis of a thin film of copper oxide on a flexible copper substrate through electrodeposition was carried out to produce a flexible and lightweight supercapacitor. The supercapacitor's performance was evaluated using cyclic voltammetry (CV) and galvanostatic charge–discharge analysis in a 1 M KOH electrolyte. The results showed that the copper oxide/copper-based supercapacitor had a large specific capacitance of 983.3 F/g and good performance even after 2200 cycles, with a capacity retention of 89.70%. The flexibility of the electrode was measured at various bending angles. The electrode showed a capacity retention of 87.5% after a 180° bending angle with a good coulombic efficiency of 79.15%. Hence, it could be a promising material for flexible supercapacitor electrodes. This demonstrates that copper oxide has great potential as a material for flexible supercapacitor electrodes. The newer applications for supercapacitors in industries such as wearable electronics, flexible displays, and energy harvesting systems can be explored.
Thick films of NiO deposited on glass substrate by screen printing technique. The nano powder of AR grade NiO was used for the preparation of thick films. The X-ray diffraction (XRD), Scanning Electron Microscopy and Electrical Characterization was carried out for unannealed and annealed films. The annealed films were at 250 0 C-400 0 C in a muffle furnace. Using characterisation techniques, the success of the synthesised nanoparticles was confirmed. The x-ray diffraction was used for structural characterization which confirms the polycrystalline nature of the films with cubic structure. From the SEM analysis the films show uniformity, roughness, large crystals and agglomeration of particles. The SEM-EDS analysed morphology and chemical compositions. The correlations between structural and morphological properties are reported. The D.C. resistance of the films was measured by half bridge method in air atmosphere at 30OC to 350OC. From the electrical parameters the NiO films shows semiconducting nature. The TCR, activation energy and sheet resistivity, specific surface area were calculated at different annealing temperatures. The electrical conductivity at room temperature was calculated as 4.56 × 𝟏𝟎 −𝟒 (𝜴 ∙ 𝒎) −𝟏
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