New inelastic X-ray scattering experiments have been performed in liquid lithium at two different temperatures: T = 475 K (slightly above the melting point) and 600 K. Taking advantage of the absence of any kinematical restriction and incoherent contribution, and pushing the instrumental resolution up to 1.5 meV, it was possible to perform an accurate investigation of the dynamic structure factor S(Q, E) in the wavevector range from 1 to 110 nm −1 . For Q smaller than Qm ≃ 25 nm −1 , the position of the main peak of the static structure factor, a detailed analysis of the lineshapes shows that any picture of the relaxation mechanisms based on a simple viscoelastic model must be abandoned. All the spectral features can instead satisfactorily be accounted for by including both fast and slow relaxation processes. The physical origin of the slow relaxation is associated to the structural rearrangement, while the local nature of the fast one is extensively discussed. At larger Q values a gradual crossover from the strongly correlated to single particle dynamics occurs, with an important weight provided by quantum effects.
New inelastic x-ray scattering experiments have been performed on liquid lithium in a wide wave vector range. With respect to the previous measurements, the instrumental resolution, improved up to 1. 5 meV, allows one to accurately investigate the dynamical processes determining the observed shape of the dynamic structure factor S(Q, omega). A detailed analysis of the line shapes shows the coexistence of relaxation processes with both slow and fast characteristic time scales, and therefore shows that pictures of the relaxation mechanisms based on a simple viscoelastic model must be abandoned.
An inelastic X-ray scattering experiment has been performed in liquid aluminum with the purpose of studying the collective excitations at wavevectors below the first sharp diffraction peak. The high instrumental resolution (up to 1.5 meV) allows an accurate investigation of the dynamical processes in this liquid metal on the basis of a generalized hydrodynamics framework. The outcoming results confirm the presence of a viscosity relaxation scenario ruled by a two timescale mechanism, as recently found in liquid lithium.
Inelastic x-ray scattering data have been collected for liquid sodium at T=390 K, i.e., slightly above the melting point. Owing to the very high instrumental resolution, pushed up to 1.5 meV, it has been possible to determine accurately the dynamic structure factor S(Q,omega) in a wide wave-vector range, 1.5-15 nm(-1), and to investigate on the dynamical processes underlying the collective dynamics. A detailed analysis of the line shape of S(Q,omega), similarly to other liquid metals, reveals the coexistence of two different relaxation processes with slow and fast characteristic time scales. The present data lead to the conclusion that (i) the picture of the relaxation mechanism based on a simple viscoelastic model fails and (ii) although the comparison with other liquid metals reveals similar behavior, the data do not exhibit an exact scaling law as the principle of the corresponding state would predict.
The longitudinal and shear viscosity of water are calculated by molecular dynamics simulation with a polarizable potential model at room temperature. To overcome the difficulty of evaluating directly the stress autocorrelation function of a system with intrinsically many-body forces, we have resorted to the analysis of the wave-vector-dependent longitudinal and transverse-current correlation functions. In a memory function formalism, the generalized viscosity can be evaluated as a function of the wave vector k. By extrapolating to k=0, we find longitudinal and shear viscosity values in better agreement with the experimental value than the corresponding quantities evaluated by making use of a nonpolarizable potential model. This result points out that for a realistic reproduction of transport quantities, it is crucial to take into account many-body contributions to the interaction potential.
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