We present hardware and software details of the pulsed molecular beam microwave Fourier transform (MB-MWFT) spectrometer used in the Kiel microwave group. We emphasize an automatic scanning facility which greatly increases the efficiency of MB-MWFT spectroscopy for the measurement of unassigned spectra.
We reinvestigated the quadrupole coupling of benzonitrile by an improved technique of microwave Fourier transform (MWFT) spectroscopy and evaluation method. The error of the coupling constants was reduced by one order of magnitude.
We present the experimental set up of a microwave Fourier-transform spectrometer for the entire K band from 18 to 26.4 GHz. It is hereby shown that this type of spectroscopy is achieved above 18 GHz. Advantages and disadvantages are discussed. The performance is illustrated by the recordings of rotational transitions of various molecules.
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