The geometries, stabilities of VGen0/- (n = 9 - 13) clusters were systematically studied by the density functional theory (DFT) using the BP86 functional and LANL2DZ basis set. Several possible multiplicities of each cluster were tested to determine the most stable structure among the isomers. The average binding energy per atom, fragmentation energy, second order energy difference and HOMO-LUMO gaps were evaluated. The results indicated that the neutral and anionic clusters possess higher stability when n = 10 and 12. The vertical detachment energy (VDE) and adiabatic detachment energy (ADE) were also calculated for anionic cluster to investigate their stabilities. Among neutral clusters, VGe10 had both the highest vertical ionization potential (VIP) and chemical hardness. Keywords BP86/LANL2DZ, binding energy, VGen0/- clusters, structure of clusters References [1] Shunping Shi, Yiliang Liu, Chuanyu Zhang, Banglin Deng, Gang Jiang (2015). A Computational Investigation of Aluminum-doped Germanium Clusters by Density Functional Theory Study. Computational and Theoretical Chemistry, 1054, pp. 8-15[2] Wen-Jie Zhao, Yuan-Xu Wang (2009). Geometries, stabilities, and Magnetic Properties of MnGen (n = 2 – 16) Clusters: Density-functional Theory Investigations. Journal of Molecular Structure: THEOCHEM, 901 (1–3), pp. 18-23.[3] Shi Shun-Ping, Liu Yi-Liang, Deng Bang-Lin, Zhang Chuan-Yu, and Jiang Gang (2016). Density Functional Theory Study of The Geometrical and Electronic Structures of (n = 1 - 9) clusters. World Scientific Publishing Company, 30, pp. 1750022-1750039.[4] J.Stato, H.Kobayashi, K. Ikarashi, N.Saito, H.Nishiyama, and Y. Inoue (2004). Photocatalitic Activity for Water Decomposition of RuO2-Dispersed Zn2GeO4 with d10 Configuration. The Journal of Physical Chemistry B, 108 (14), pp. 4369-4375.[5] Daoxin Dai, Molly Piels, and John E. Bowers (2014). Monolithic Germanium/Silicon Photodetectors With Decoupled Structures: Resonant APDs and UTC Photodiodes. IEEE Journal of Selected Topics in Quantum Electronics, 20 (6), pp. 3802214-3802227.[6] Chia-Yun Chou, Gyeong S. Hwang (2014). On The Origin of The Significant Difference in Lithiation Behavior Between Silicon and Germanium. Journal of Power Sources, 263, pp. 252-258.[7] Siwen Zhang, Bosi Yin, Yang Jiao, Yang Liu, Xu Zhang, Fengyu Qu, Ahmad Umar, Xiang Wu (2014). Ultra-long Germanium Oxide Nanowires: Structures and Optical Properties. Journal of Alloys and Compounds, 606, pp. 149-153.[8] T. Herrmannsdörfer, V. Heera, O. Ignatchik, M. Uhlarz, A. Mücklich, M. Posselt, H. Reuther, B. Schmidt, K.-H. Heinig, W. Skorupa, M. Voelskow, C. Wündisch, R. Skrotzki, M. Helm, and J. Wosnitza (2009).Superconducting State in a Gallium-Doped Germanium Layer at Low Temperatures. Physical Review Letters, 102, pp. 217003-217006.[9] Vijay Kumar, and Yoshiyuki Kawazoe (2002). Metal-Encapsulated Caged Clusters of Germanium with Large Gaps and Different Growth Behavior than Silicon. Physical Review Letters, 88, pp. 235504-235507.[10] Xiao-Jiao Deng, Xiang-Yu Kong, Hong-Guang Xu, Xi-Ling Xu, Gang Feng, and Wei-Jun Zheng (2015). Photoelectron Spectroscopy and Density Functional Calculations of VGen- (n = 3 − 12) Clusters. The Journal of Physical Chemistry C, 119 (20), pp. 11048-11055.[11] John P. Perdew, Kieron Burke, and Matthias Ernzerhof (1996).Generalized Gradient Approximation Made Simple. Physical Review Letters, 77, pp. 3865-3868.[12] Chaouki Siouani, Sofiane Mahtout, Sofiane Safer, and Franck Rabilloud (2017).Structure, Stability and Electronic and Magnetic Properties of VGen (n = 1 - 19) Clusters. The Journal of Physical Chemistry A, 121 (18), pp. 3540-3554.[13] Jin Wang, and Ju-Guang Han (2006).A Theoretical Study on Growth Patterns of Ni-Doped Germanium Clusters.The Journal of Physical Chemistry B, 110 (15), pp. 7820-7827.[14] Debashis Bandyopadhyay and Prasenjit Sen (2010). Density Functional Investigation of Structure and Stability of Gen and GenNi (n = 1 − 20) Clusters: Validity of the Electron Counting Rule. The Journal of Physical Chemistry A, 114 (4), pp. 1835-1842[15] Soumaia Djaadi, Kamal Eddine Aiadi, and Sofiane Mahtout (2018). Frist Principles Study of Structural, electronic and magnetic properties of (n = 1 - 17) clusters. Journal of Semiconductors, 39 (4), pp. 42001-420013.[16] İskender Muz,Mustafa Kurban,Kazım Şanlıc (2018). Analysis of the Geometrical Properties and Electronic Structure of Arsenide Doped Boron Cluster: Ab-initio approach. Inorganica Chimica Acta, 474, pp. 66-72.[17] Axel D. Becke (1988). Density-functional exchange - energy approximation with correct asymptotic behavior.Physical Review A, 38, pp. 3098-3100.[18] Willard R. Wadt, P. Jeffrey Hay (1985). Ab initio effective core potentials for molecular calculations.Potentials for main group elements Na to Bi.The Journal of Chemical Physics, 82 (1), pp. 284-298.[19] Willard R. Wadt, P. Jeffrey Hay (1985). Ab initio effective core potentials for molecular calculations.Potentials for K to Au including the outermost core orbitals.The Journal of Chemical Physics, 82 (1), pp. 299-310.[20] Willard R. Wadt, P. Jeffrey Hay (1985). Ab initio effective core potentials for molecular calculations. Potentials for the transition metal atoms Sc to Hg. The Journal of Chemical Physics, 82 (1), pp. 270-283.[21] Gabriele Manca, Samia Kahla, Jean-Yves Saillard, Rémi Marchal, Jean-François Halet (2017). Small Ligated Organometallic Pdn Clusters (n = 4 - 12): A DFT Investigation. Journal of Cluster Science, 28 (2), pp. 853-868.[22] Tran Dieu Hang, Huynh Minh Hung, Lam Ngoc Thiem. Hue M. T. Nguyen (2015). Electronic structure and thermochemical properties of neutral and anionic rhodium clusters Rhn, n = 2 – 13. Evolution of structures and stabilities of binary clusters RhmM (M = Fe, Co, Ni; m = 1 – 6). Computational and Theoretical Chemistry, 1068, pp. 30–41.[23] Michael J. Frisch, et al. (2010). Gaussian 09, Revision C.01.Gaussian, Inc., Wallingford CT.
Geometries associated relative stabilities, averaged binding energy, fragmentation energy, second-order energy difference and energy gaps of V-doped germanium cationic clusters GenV+ (n = 9-13) have been investigated by using density functional theory with the BP86 exchange-correlation potential and effective core potential (ECP) LanL2DZ basis sets. Natural population analysis charge is also examined to understand the associated charge transfer in structures of clusters. When an electron is removed from neutral cluster GenV to form the cation cluster GenV+, geometric structure of the lowest energy isomers change. The endohedral cage structure of the cation clusters appears at n = 10 in the cluster Ge10V+. The lowest energy isomers of cation cluster are in triplet state or singlet state. The cluster Ge10V+ is found to be the most stable in terms of stability parameters in the all system GenV+ (n = 9 - 13). Keywords: BP86/LANL2DZ, binding energy, V-Ge clusters, structure of clusters. References [1] T. Fehlner, J. Halet, J. Saillard, Molecular Clusters: A Bridge to Solid-State Chemistry, Cambridge University Press, Cambridge, 2007. https://doi.org/10.1017/CBO9780511628887.[2] S. Djaadi, K. Eddine Aiadi, S. Mahtout, First principles study of structural, electronic and magnetic properties of SnGen(0, ±1) (n = 1–17) clusters, J. Semicond., 39(4) (2018) 42001. https://doi.10.1088/1674-4926/39/4/042001.[3] P.N. Samanta, K.K. Das, Electronic structure, bonding, and properties of SnmGen (m+n≤5) clusters: A DFT study, Comput. Theor. Chem., 980 (2012) 123-132. https://doi.org/10.1016/j. comptc.2011.11.038.[4] S. Mahtout, Y. Tariket, Electronic and magnetic properties of CrGen (15≤n≤29) clusters: A DFT study, Chem. Phys., 472 (2016) 270-277. https://doi.org/10.1016/j.chemphys.2016.03.011.[5] A.A. Shvartsburg, B. Liu, Z. Y. Lu, C. Z. Wang, M.F. Jarrold, K. M. Ho, Structures of Germanium Clusters: Where the Growth Patterns of Silicon and Germanium Clusters Diverge, Phys. Rev. Lett., 83(11) (1999) 2167-2170. https://doi.org/ 10.1103/PhysRevLett.83.2167.[6] S. Bals, S. Van Aert, C. P. Romero, et al., Atomic scale dynamics of ultrasmall germanium clusters, Nat. Commun., 3 (2012) 897. https://doi.org/10. 1038/ncomms1887.[7] J. De Haeck, T. B. Tai, S. Bhattacharyya, et al., Structures and ionization energies of small lithium doped germanium clusters, Phys. Chem. Chem. Phys., 15(14) (2013) 5151-5162. https:// doi.org/ 10.1039/C3CP44395G.[8] G.R. Burton, C. Xu, D.M. Neumark, Study of small semiconductor clusters using anion photoelectron spectroscopy: germanium clusters, Surf. Rev. Lett., 03(01) (1996) 383-388. https:// doi.org/10.1142/S0218625X96000693.[9] P.W. Deutsch, L.A. Curtiss, J.P. Blaudeau, Electron affinities of germanium anion clusters, Gen− (n=2–5), Chem. Phys. Lett., 344(1) (2001) 101-106. https://doi.org/10.1016/S0009-2614(01) 00734-5.[10] J. Wang, G. Wang, J. Zhao, Structure and electronic properties of Gen (n=2-5) clusters from density-functional theory, Phys. Rev. B., 64(20) (2001) 205411. https://doi.org/10.1103/PhysRevB. 64.205411.[11] W.J. Zhao, Y.X. Wang, Geometries, stabilities, and magnetic properties of MnGen (n=2–16) clusters: Density-functional theory investigations, J. Mol. Struct. THEOCHEM., 901(1) (2009)18-23. https://doi.org/10.1016/j.theochem.2008.12.039.[12] W.J. Zhao, Y.X. Wang, Geometries, stabilities, and electronic properties of FeGen (n=9–16) clusters: Density-functional theory investigations, Chem. Phys., 352(1) (2008) 291-296. https://doi. org/10.1016/j.chemphys.2008.07.006.[13] S. Shi, Y. Liu, C. Zhang, B. Deng, G. Jiang G, A computational investigation of aluminum-doped germanium clusters by density functional theory study, Comput. Theor. Chem., 1054 (2015) 8-15. https://doi.org/10.1016/j.comptc.2014.12.004.[14] X. Li, K. Su, X. Yang, L. Song, L. Yang, Size-selective effects in the geometry and electronic property of bimetallic Au–Ge nanoclusters, Comput. Theor. Chem., 1010 (2013) 32-37. https:// doi.org/10.1016/j.comptc.2013.01.012.[15] N. Kapila, V.K. Jindal, H. Sharma, Structural electronic and magnetic properties of Mn, Co, Ni in Gen for (n=1–13), Phys. B Condens. Matter., 406(24) (2011) 4612-4619. https://doi.org/10. 1016/j.physb.2011.09.038.[16] C. Tang, M. Liu, W. Zhu, K. Deng, Probing the geometric, optical, and magnetic properties of 3d transition-metal endohedral Ge12M (M=Sc–Ni) clusters, Comput. Theor. Chem., 969(1) (2011) 56-60.https://doi.org/10.1016/j.comptc.2011.05.012.[17] A.K. Singh, V. Kumar, Y. Kawazoe, Metal encapsulated nanotubes of germanium with metal dependent electronic properties, Eur. Phys. J. D-Atomic, Mol Opt Plasma Phys., 34(1-3) (2005) 295-298. https://doi.org/10.1140/epjd/e2005-00162-1.[18] X.J. Deng, X. Y. Kong, H. G. Xu, X. L. Xu, G. Feng, W. J. Zheng, Photoelectron Spectroscopy and Density Functional Calculations of VGen– (n = 3–12) Clusters, J. Phys. Chem. C, 119(20) (2015) 11048-11055. https://doi.org/10.1021/jp 511694c.[19] C. Siouani, S. Mahtout, S. Safer, F. Rabilloud, Structure, Stability, and Electronic and Magnetic Properties of VGen (n = 1–19) Clusters, J. Phys. Chem. A, 121(18) (2017) 3540-3554. https://doi. org/10.1021/acs.jpca.7b00881.[20] S.P. Shi, Y.L. Liu, B.L. Deng, C.Y. Zhang, G. Jiang, Density functional theory study of the geometrical and electronic structures of GenV(0,±1)(n=1–9) clusters, Int. J. Mod. Phys. B, 31(05) (2016) 1750022. https://doi.org/10.1142/ S0217979217500229.[21] N. Huu Tho, T.T. Tu, T.M. Nhan, P.H. Cam, P.T. Thi, The Geometries and Stabilities of Neutral and Anionic Vanadium-Doped Germanium Clusters VGen0/- (n = 9-13): A Density Functional Theory Investigation, VNU J. Sci. Nat. Sci. Technol. 35(1) (2019) 47-56. https://doi.org/10. 25073/2588-1140/vnunst.4827.[22] W.R. Wadt, P.J. Hay, Ab initio effective core potentials for molecular calculations. Potentials for main group elements Na to Bi, J. Chem. Phys., 82(1)(1985)284-298. https://doi.org/10.1063/1.448800[23] P.J. Hay, W.R. Wadt, Ab initio effective core potentials for molecular calculations. Potentials for K to Au including the outermost core orbitals, J. Chem. Phys., 82(1) (1985) 299-310. https://doi. org/10.1063/1.448975.[24] P.J. Hay, W.R. Wadt, Ab initio effective core potentials for molecular calculations. Potentials for the transition metal atoms Sc to Hg, J. Chem. Phys., 82(1) (1985) 270-283. https://doi.org/10. 1063/1.448799.[25] G. Manca, S. Kahlal, J.Y. Saillard, R. Marchal, J. F. Halet, Small Ligated Organometallic Pdn Clusters (n=4−12): A DFT Investigation, J. Clust. Sci., 28(2) (2017) 853-868. https://doi.org/10. 1007/s10876-017-1168-2.[26] T.D. Hang, H.M. Hung, L.N. Thiem, H.M.T. Nguyen, Electronic structure and thermochemical properties of neutral and anionic rhodium clusters Rhn, n=2–13. Evolution of structures and stabilities of binary clusters RhmM (M=Fe, Co, Ni; m=1–6), Comput. Theor. Chem., 1068 (2015) 30-41. https://doi.org/10.1016/j.comptc.2015.06. 004.[27] M.J. Frisch H.B. Schlegel, G.E. Scuseria, M.A. Robb, J.R. Cheeseman, G. Scalmani, V. Barone, G.A. Petersson, H. Nakatsuji, X. Li, M. Caricato, A. Marenich, J. Bloino, B. G. Janesko, R. Gomperts, B. Mennucci, H. P. Hratchian, J. V. Ortiz, A. F. Izma GWT. Gaussian 09, Revision C.01. Gaussian, Inc, Wallingford CT. 2010.[28] A.E. Reed, L.A. Curtiss, F. Weinhold, Intermolecular interactions from a natural bond orbital, donor-acceptor viewpoint, Chem. Rev., 88(6) (1988) 899-926. https://doi.org/10.1021/ cr00088a005.
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