Single-molecule fluorescence photoswitching plays an essential role in ultrahigh-density (Tbits/inch 2 ) optical memories and super-high-resolution fluorescence imaging. Although several fluorescent photochromic molecules and fluorescent proteins have been applied, so far, to optical memories and super-highresolution imaging, their performance is unsatisfactory because of the absence of "non-destructive fluorescence readout capability". Here we report on a new molecular design principle of a molecule having non-destructive readout capability. The molecule is composed of acceptor photochromic diarylethene and donor fluorescent perylenebisimide units. The fluorescence is reversibly quenched when the diarylethene unit converts between the open-and the closed-ring isomers upon irradiation with visible and UV light. The fluorescence quenching is based on an electron transfer from the donor to the acceptor units. The fluorescence photoswitching and non-destructive readout capability were demonstrated in solution (an ensemble state) and at the single-molecule level. Femtosecond time-resolved transient and fluorescent lifetime measurements confirmed that the fluorescence quenching is attributed to the intramolecular electron transfer.

Photoactive molecules that reversibly switch upon visible light irradiation are one of the most attractive targets for biological as well as imaging applications. One possible approach to prepare such photoswitches is to extend π-conjugation length of molecules and shift the absorption bands to longer wavelengths. Although several attempts have been demonstrated based on this approach for diarylethene (DAE) photoswitches, photoreactivity of the DAE derivatives is dramatically suppressed when the conjugation length is extended by connecting aromatic dyes at the side positions of aryl groups in the DAE unit. In this study, we successfully prepared a visible-light reactive DAE derivative by introducing an aromatic dye at the reactive carbon atom of the DAE unit, optimizing orbital level of each component, and controlling the mutual orientation of the aromatic dye and the DAE unit. The DAE derivative (3) undergoes a photocyclization reaction upon irradiation with 560 nm light and the closed-isomer converts to the open-ring isomer upon irradiation with 405 nm light. The high photoconversion yields (>90%) were achieved for both photocyclization and photocycloreversion reactions. The photoreactivity induced by visible light irradiation and the molecular design strategy were discussed based on theoretical calculations.

A bilateral teleoperation experiment with Engineering Test Satellite 7 (ETS-VII) was conducted on November 22, 1999. Round-trip time for communication between the National Space Development Agency of Japan ground station and the ETS-VII was approximately seven seconds. We constructed a bilateral teleoperator that is stable, even under such a long time delay. Several experiments, such as slope-tracing task and peg-in-hole task, were carried out. Task performance was compared between the bilateral mode and the unilateral mode with force telemetry data visually displayed on a screen. All tasks were possible by bilateral control without any visual information. Experimental results showed that kinesthetic force feedback to the operator is helpful even under such a long time delay, and improves the performance of the task.

MgB 2 superconductor has a great potential for applications because of its high Tc and Bc2, exceeding those of any Nb-base superconductors at any temperature. It is now important to understand its flux pinning so as to raise Jc to high values over a wide field range. We show that nanometer-sized columnar-grain structure can produce Jc exceeding 5×106A∕cm2. The angular dependence of Jc indicates that the strongest pinning occurs when the field is aligned parallel to the grain boundaries. Our results confirm earlier deductions that grain boundaries in MgB2 act as effective pinning centers like those in Nb3Sn.

Two types of fluorescent diarylethene-perylenebisimide dyads were synthesized and their photochromic performance was studied. The dyads showed an unexpected photochromic reactivity. The photocyclization reaction takes place upon irradiation with visible light (>500 nm), where the diarylethene unit has no absorption. Inferring from the excitation wavelength dependence and oxygen effect, the triplet states of the diarylethene unit are considered to play an essential role in the photocyclization reaction with visible (>500 nm) light. † Part of the "Hiroshi Masuhara Festschrift".

No abstract

No abstract

No abstract