The electrical circuit for the recently developed transient plane source (TPS) technique for fast and precise measurements of thermal tramport properties of solids has been modified for more convenient 8nd more automated measurements. The technique has been tested for measurements of thermal conductivity and thermal diffusivity for a series of building materials ranging from thermally insulating materials (extruded polystyrene and PMMA) to good thermal conductors (stainless steel and aluminium). The results obtained in this work agree well with other techniques and international standrrrd materials This agreement indicates that the TPS method is accurate to within f 5% over a thermal conductivity range of four orders of magnitude (0.02 W m K to 2QO W m K I).
Abstract. Parameters leading to the severity of the fire in Laerdalsøyri, Norway, January 18th to 19th 2014, have been analyzed. The fire in the first villa developed significantly faster than the fire fighters could handle and the fire quickly spread to other structures. In addition to 36 modern buildings, 4 historic buildings in Gamle Laerdalsøyri cultural heritage area were lost. Heroic effort of local and neighbor community fire brigades, police, military forces and volunteers prevented the fire from destroying the whole village, including the remaining 157 historic buildings. Adiabatically heated (low humidity) air from surrounding high mountains gave outdoor wood fuel moisture content (FMC) of about 7.6%. Inside inhabited buildings, it is shown that the wooden products reached about 4.5% FMC prior to the blaze. When ignited, this resulted in rapid fire development. Two story villas burned down in less than 1 h while producing much embers and firebrands. Strong shifting winds subsequently spread the fire to neighbor houses by flame contact (periodically 20 m long horizontal flames) and over long distances (200 m) by embers and firebrands. Based on the present work, an increased fire risk associated with low FMC in inhabited wooden houses during winter time can be predicted. This is of value when considering measures to reduce the probability of a fire outbreak as well as measures mitigating the escalation of a potential fire.
It has recently been demonstrated that 50 mm thick industrial grade thermal insulation may serve as passive fire protection of jet fire exposed thick walled steel distillation columns. The present study investigates the performance of thermal insulation in conjunction to 3 mm, 6 mm, 12 mm and 16 mm steel walls, i.e., where the wall represents less heat sink, when exposed to 350 kW/m2 heat load. Regardless of the tested steel plate thicknesses, about 10 min passed before a nearly linear steel temperature increase versus time was observed. Thereafter, the thinnest plates systematically showed a faster temperature increase than the thickest plates confirming the wall heat sink effect. To study thermal insulation sintering, 50 mm thermal insulation cubes were heat treated (30 min holding time) at temperatures up to 1100 °C. No clear sign of melting was observed, but sintering resulted in 25% shrinkage at 1100 °C. Thermogravimetric analysis to 1300 °C revealed mass loss peaks due to anti-dusting material at 250 °C and Bakelite binder at 460 °C. No significant mass change occurred above 1000 °C. Differential scanning calorimetry to 1300 °C revealed endothermic processes related to the anti-dusting material and Bakelite mass losses, as well as a conspicuous endothermic peak at 1220 °C. This peak is most likely due to melting. The endothermic processes involved when heating the thermal insulation may to a large part explain the 10 min delay in steel plate temperature increase during fire testing. Overall, the tested thermal insulation performed surprisingly well also for protecting the thin steel plates.
Abstract:In the oil and gas industry, hydrocarbon process equipment was previously often thermally insulated by applying insulation directly to the metal surface. Fire protective insulation was applied outside the thermal insulation. In some cases, severe corrosion attacks were observed due to ingress of humidity and condensation at cold surfaces. Introducing a 25 mm air gap to prevent wet thermal insulation and metal wall contact is expected to solve the corrosion issues. This improved insulation methodology does, however, require more space that may not be available when refurbishing older process plants. Relocating structural elements would introduce much hot work, which should be minimized in live plants. It is also costly. The aim of the present study is therefore to develop a test concept for testing fire resistance of equipment protected with only air-gap and thermal insulation, i.e., without the fire-protective insulation. The present work demonstrates a conceptual methodology for small scale fire testing of mockups resembling a section of a distillation column. The mockups were exposed to a small-scale propane flame in a test configuration where the flow rate and the flame zone were optimized to give heat flux levels in the range 250-350 kW/m 2 . Results are presented for a mockup resembling a 16 mm thick distillation column steel wall. It is demonstrated that the modern distance insulation in combination with the heat capacity of the column wall indicates 30+ minutes fire resistance. The results show that this methodology has great potentials for low cost fire testing of other configurations, and it may serve as a set-up for product development.
Biofuel heaters and fireplaces have in recent years been introduced for indoor and outdoor use. Due to their simplicity, they are usually equipped with few or no safety features. Worldwide, incidents resulting in major skin burn injury and long hospitalization periods have occurred when using such biofuel units. The present study analyses the characteristics of the liquids ethanol and methanol to get a scientific background for understanding related accidents. The comparably heavy vapors, especially from ethanol, may generate a pillow of combustible gas in the vicinity of the unit, particularly in quiescent indoor air conditions. It is also revealed that these fuels represent a potential severe risk, since the equilibrium vapor pressures are close to the stoichiometric fuel–air composition at normal room temperatures. Selected incidents were reviewed to understand the mechanisms involved when severe burns were received by the users. It turns out that the most severe incidents were related to refilling operations and included ignition of the fuel container vapor phase. When ignited, the container gas phase expansion propelled burning fuel from the bottle or container onto the user or other persons in the vicinity. Similar incidents involving refilling methanol for chemistry demonstrations and ethanol for endodontic (dentistry) treatment were also studied and it was shown that these accidents followed similar accident mechanisms. It may be concluded that the main contributors to burn risk are the near-stoichiometric vapor pressure of these liquids at room temperature and the close proximity of the fuel container to burning fuel. Research needs and possible technical barriers are suggested to reduce this risk for the future.
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