HPLC analysis of the stabilizer is one of the major methods in use for surveillance testing of diphenylamine (DPA) stabilized propellants. Often 0.2% DPA is used as a minimum content for safe propellants. In most cases the propellant can be stored much longer after this limit has been reached without any risk for self‐ignition. We report here about a reaction where DPA bonds to nitrocellulose, leaving a non extractable aromatic stabilizing compound left in the propellant, resulting in a longer time to autocatalysis than predicted. Diphenylnitramine is discussed as a possible intermediary compound occurring from the reaction between DPA and nitrocellulose. This should add to a better understanding of the degradation processes in propellants.

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