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Abstract. Time series of monthly, seasonal and annual mean air temperature, precipitation, snow cover duration and specific runoff of rivers in Estonia are analysed for detecting of trends and regime shifts during 1951-2015. Trend analysis is realised using the Mann-Kendall test and regime shifts are detected with the Rodionov test (sequential t-test analysis of regime shifts). The results from Estonia are related to trends and regime shifts in time series of indices of large-scale atmospheric circulation. Annual mean air temperature has significantly increased at all 12 stations by 0.3-0.4 K decade −1 . The warming trend was detected in all seasons but with the higher magnitude in spring and winter. Snow cover duration has decreased in Estonia by 3-4 days decade −1 . Changes in precipitation are not clear and uniform due to their very high spatial and temporal variability. The most significant increase in precipitation was observed during the cold half-year, from November to March and also in June. A time series of specific runoff measured at 21 stations had significant seasonal changes during the study period. Winter values have increased by 0.4-0.9 L s −1 km −2 decade −1 , while stronger changes are typical for western Estonia and weaker changes for eastern Estonia. At the same time, specific runoff in April and May have notably decreased indicating the shift of the runoff maximum to the earlier time, i.e. from April to March. Air temperature, precipitation, snow cover duration and specific runoff of rivers are highly correlated in winter determined by the large-scale atmospheric circulation. Correlation coefficients between the Arctic Oscillation (AO) and North Atlantic Oscillation (NAO) indices reflecting the intensity of westerlies, and the studied variables were 0.5-0.8. The main result of the analysis of regime shifts was the detection of coherent shifts for air temperature, snow cover duration and specific runoff in the late 1980s, mostly since the winter of 1988/1989, which are, in turn, synchronous with the shifts in winter circulation. For example, runoff abruptly increased in January, February and March but decreased in April. Regime shifts in annual specific runoff correspond to the alternation of wet and dry periods. A dry period started in 1964 or 1963, a wet period in 1978 and the next dry period at the beginning of the 21st century.

Biomass is defined as organic matter from living organisms represented in all kingdoms. It is recognized to be an excellent source of proteins, polysaccharides and lipids and, as such, embodies a tailored feedstock for new products and processes to apply in green industries. The industrial processes focused on the valorization of terrestrial biomass are well established, but marine sources still represent an untapped resource. Oceans and seas occupy over 70% of the Earth’s surface and are used intensively in worldwide economies through the fishery industry, as logistical routes, for mining ores and exploitation of fossil fuels, among others. All these activities produce waste. The other source of unused biomass derives from the beach wrack or washed-ashore organic material, especially in highly eutrophicated marine ecosystems. The development of high-added-value products from these side streams has been given priority in recent years due to the detection of a broad range of biopolymers, multiple nutrients and functional compounds that could find applications for human consumption or use in livestock/pet food, pharmaceutical and other industries. This review comprises a broad thematic approach in marine waste valorization, addressing the main achievements in marine biotechnology for advancing the circular economy, ranging from bioremediation applications for pollution treatment to energy and valorization for biomedical applications. It also includes a broad overview of the valorization of side streams in three selected case study areas: Norway, Scotland, and the Baltic Sea.

The main components of landfill gas are methane and carbon dioxide. Emissions of methane, a strong greenhouse gas, can be minimized by in situ oxidation in the bioactive cover layer. Typically, organic-rich porous materials such as compost are used for this process. In this study, the material for a biocover was obtained from the same landfill by landfill mining. The objective was to study the spatial distribution of gases and the efficiency of methane degradation in the biocover. The methane and carbon dioxide emissions were measured at 29 measuring points six times on the surface and once at a depth of 0.5 m. The highest values of both gases from the surface were recorded in July 2015: 1.0% for CO2 and 2.1% for CH4. Deeper in the cover layer, higher values of methane concentration were recorded. The results showed that (a) methane from the waste deposit was entering the biocover, (b) the migration of methane to the atmosphere was low, (c) fluctuations in the composition of gases are seasonal, and (d) the trend in the concentration of CH4 over time was an overall decrease. The described cover design reduces the CH4 emissions in landfills using elements of circular economy—instead of wasting natural soils and synthetic liners for the construction of the final cover layer, functional waste-derived materials can be used.