Analytical theory is developed for ECE and DISP1 reactions
occurring at channel electrodes. Simple
expressions are presented which allow the ready mechanistic
interpretation of experimental data and the
deduction of corresponding rate constants. These are shown to be
in excellent agreement with numerical
simulations and with experiments conducted on the reductions of
o-bromonitrobenzene in dimethylformamide
solution and of p-bromonitrobenzene in acetonitrile in the
presence of light of wavelength 325 nm.
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