We demonstrate cantilever-enhanced photoacoustic spectroscopy in the mid-infrared using a supercontinuum source. The approach is broadband, compact, and allows for higher photoacoustic signal intensity and enhanced signal-to-noise ratio as compared to systems employing conventional back body radiation sources. Using this technique, we perform spectroscopic measurements of the full ro-vibrational band structure of water vapor at 1900 nm and methane at 3300 nm with relative signal enhancement factors of 70 and 19, respectively, when compared to measurements that use a black body radiation source. Our results offer novel perspective for photoacoustic detection opening the door to compact and sensitive broadband analyzers in the mid-infrared spectral region.
Optical frequency comb photoacoustic spectroscopy (OFC-PAS) is demonstrated for the first time for broadband high-resolution trace gas analysis in small sample volumes.
We report multipass broadband photoacoustic spectroscopy of trace gases in the mid-infrared. The measurement principle of the sensor relies on supercontinuum-based Fourier transform photoacoustic spectroscopy (FT-PAS), in which a scanning...
We report the first photoacoustic detection scheme using an optical frequency comb-optical frequency comb photoacoustic spectroscopy (OFC-PAS). OFC-PAS combines the broad spectral coverage and the high resolution of OFCs with the small sample volume of cantilever-enhanced PA detection. In OFC-PAS, a Fourier transform spectrometer (FTS) is used to modulate the intensity of the exciting comb source at a frequency determined by its scanning speed. One of the FTS outputs is directed to the PA cell and the other is measured simultaneously with a photodiode and used to normalize the PA signal. The cantileverenhanced PA detector operates in a non-resonant mode, enabling detection of a broadband frequency response. The broadband and the high-resolution capabilities of OFC-PAS are demonstrated by measuring the rovibrational spectra of the fundamental C-H stretch band of CH 4 , with no instrumental line shape distortions, at total pressures of 1000 mbar, 650 mbar, and 400 mbar. In this first demonstration, a spectral resolution two orders of magnitude better than previously reported with broadband PAS is obtained, limited by the pressure broadening. A limit of detection of 0.8 ppm of methane in N 2 is accomplished in a single interferogram measurement (200 s measurement time, 1000 MHz spectral resolution, 1000 mbar total pressure) for an exciting power spectral density of 42 mW/cm À1 . A normalized noise equivalent absorption of 8 Â 10 À10 W cm À1 Hz À1/2 is obtained, which is only a factor of three higher than the best reported with PAS based on continuous wave lasers. A wide dynamic range of up to four orders of magnitude and a very good linearity (limited by the Beer-Lambert law) over two orders of magnitude are realized. OFC-PAS extends the capability of optical sensors for multispecies trace gas analysis in small sample volumes with high resolution and selectivity.
We investigate the noise transfer mechanism from the light source intensity fluctuations to the acoustic signal in Fourier transform photoacoustic spectroscopy (FT-PAS). This noise coupling is expected to be reduced in FT-PAS compared with conventional Fourier transform spectroscopy, as only the specific spectral components that are absorbed by the probed sample contribute to the noise level. We employ an incoherent supercontinuum (SC) light source in our experiments and observe a linear relation between the sample gas concentration and the detected noise level, which significantly reduces the influence of the SC noise on the detection limit. Based on our experimental results, we derive a model for the noise level, which establishes the foundation for practical sensitive implementation of FT-PAS.
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