The annual potential of waste biomass production from food processing in Europe is 16.9 million tonnes. Unfortunately, most of these organic wastes are utilized without the energy gain, mainly due to the high moisture content and the ability to the fast rotting and decomposition. One of the options to increase its value in terms of energy applications is to valorize its properties. Torrefaction process is one of the pre-treatment technology of raw biomass that increases the quality of the fuel, especially in the context of resistance to moisture absorption. However, little is known about the influence of torrefaction temperature on the degree of valorization of some specific waste biomass. The aim of this paper was to analyze the influence of the temperature of the torrefaction on the hydrophobic properties of waste biomass, such as black currant pomace, apple pomace, orange peels, walnut shells, and pumpkin seeds. The torrefaction process was carried out at temperatures of 200 °C, 220 °C, 240 °C, 260 °C, 280 °C, and 300 °C. The hydrophobic properties were analyzed using the water drop penetration time (WDPT) test. The torrefied waste biomass was compared with the raw material dried at 105 °C. The obtained results revealed that subjecting the biomass to the torrefaction process improved its hydrophobic properties. Biomass samples changed their hydrophobic properties from hydrophilic to extremely hydrophobic depending on the temperature of the process. Apple pomace was the most hydrophilic sample; its water drop penetration was under 60 s. Black currant and apple pomaces reached extremely hydrophobic properties at a temperature of 300 °C, only. In the case of orange peels, walnut shells, and pumpkin seeds, already at the temperature of 220 °C, the samples were characterized by severely hydrophobic properties with a penetration time over 1000 s. At the temperature of 260 °C, orange peels, walnut shells, and pumpkin seeds reached extremely hydrophobic properties. Furthermore, in most cases, the increase of torrefaction temperature improved the resistance to moisture absorption, which is probably related to the removal of hydroxyl groups and structural changes occurring during this thermal process.
The global energy system needs new, environmentally friendly, alternative fuels. Biomass is a good source of energy with global potential. Forestry biomass (especially wood, bark, or trees fruit) can be used in the energy process. However, the direct use of raw biomass in the combustion process (heating or electricity generation) is not recommended due to its unstable and low energetic properties. Raw biomass is characterized by high moisture content, low heating value, and hydrophilic propensities. The initial thermal processing and valorization of biomass improves its properties. One of these processes is torrefaction. In this study, forestry biomass residues such as horse chestnuts, oak acorns, and spruce cones were investigated. The torrefaction process was carried out in temperatures ranging from 200 °C to 320 °C in a non-oxidative atmosphere. The raw and torrefied materials were subjected to a wide range of tests including proximate analysis, fixed carbon content, hydrophobicity, density, and energy yield. The analyses indicated that the torrefaction process improves the fuel properties of horse chestnuts, oak acorns, and spruce cones. The properties of torrefied biomass at 320 °C were very similar to hard coal. In the case of horse chestnuts, an increase in fixed carbon content from 18.1% to 44.7%, and a decrease in volatiles from 82.9% to 59.8% were determined. Additionally, torrefied materials were characterized by their hydrophobic properties. In terms of energy yield, the highest value was achieved for oak acorns torrefied at 280 °C and amounted to 1.25. Moreover, higher heating value for the investigated forestry fruit residues ranged from 24.5 MJ·kg−1 to almost 27.0 MJ·kg−1 (at a torrefaction temperature of 320 °C).
The European Union created a European Green Deal Program (EGDP). This program aims at a sustainable economy through the transformation of the challenges related to climate and the environment. The main goal of EGDP is climate neutrality by 2050. The increase of alternative biomass residues utilization from various food processing industries and cooperation in the energy and waste management sector is required to meet these expectations. Nut shells are one of the lesser-known, yet promising, materials that can be used as an alternative fuel or a pre-treated product to further applications. However, from a thermal conversion point of view, it is important to know the energy properties and kinetic parameters of the considered biowaste. In this study, the energy and kinetic parameters of walnut, hazelnut, peanut, and pistachio shells were investigated. The results showed that raw nut shells are characterized by useful properties such as higher heating value (HHV) at 17.8–19.7 MJ∙kg−1 and moisture content of 4.32–9.56%. After the thermal treatment of nut shells (torrefaction, pyrolysis), the HHV significantly increased up to ca. 30 MJ∙kg−1. The thermogravimetric analysis (TGA) applying three different heating rates (β; 5, 10, and 20 °C∙min−1) was performed. The kinetic parameters were determined using the isothermal model-fitting method developed by Coats–Redfern. The activation energy (Ea) estimated for β = 5 °C∙min−1, was, e.g., 60.3 kJ∙mol−1∙K−1 for walnut, 59.3 kJ∙mol−1∙K−1 for hazelnut, 53.4 kJ∙mol−1∙K−1 for peanut, and 103.8 kJ∙mol−1∙K−1 for pistachio, respectively. Moreover, the increase in the Ea of nut shells was observed with increasing the β. In addition, significant differences in the kinetic parameters of the biomass residues from the same waste group were observed. Thus, characterization of specific nut shell residues is recommended for improved modeling of thermal processes and designing of bioreactors for thermal waste treatment.
The interest in pellets utilization for households heating has been growing significantly in the last several years. However, the pellets need to meet certain quality requirements, including the mechanical durability (DU) index. In the winter seasons, the pellets are very often stored in unheated in-door systems or are transported by trucks over long distances. As a result, the pellets are exposed to external weather factors, including very low temperatures (even freezing ones), which can have a negative impact on the quality parameters of the fuel. There are several parameters affecting mechanical durability, but little is known about the influence of a very low temperature on the pellet properties. The aim of this research was to analyze the influence of freezing temperature storage on the mechanical durability of commercial pellets made of different biomass. The research was carried out in accordance with the international standard for solid biofuels PN-EN ISO 17831-1:2016-02. The samples were investigated under three different conditions: after normal storage conditions (20 °C), after frozen storage conditions (−28 °C) and after the defrosting of the pellets. The results revealed that the freezing process and subsequent defrosting of the pellets only causes a small drop in their mechanical durability in comparison to the normal storage conditions. The highest mechanical durability was established for digestate pellet and pine sawdust pellet, at 99.0 ± 0.1% and 98.7 ± 0.1% respectively (p < 0.05). The greatest change of mechanical durability was observed after the defrosting process of pellets, which in the initial stage and at the normal storage temperature were characterized by low mechanical durability. The pellets made of sunflower husk (DU = 87.4%) and coal/straw blend (DU = 96.2%) were distinguished by the highest change in their mechanical durability (ΔDU = 1.7%, p < 0.05). Based on the obtained results, it was concluded that the storage of pellets at freezing temperature does not significantly affect their mechanical durability. However, if the mechanical durability decreases, this result is related to pellets with low initial mechanical durability.
A large portion of food loss and waste (FSL) is comprised of seeds and stones. Exotic fruits such as mangoes, lychees and avocados, in which the seeds account for a significant part of the weight and volume of the entire product, are most affected by this problem. The seeds contain a large quantity of polyphenols and essential nutrients, which makes them a good material for extraction. However, conventional extraction techniques are considered time-consuming, and therefore significantly limit their use on an industrial scale. An alternative method of managing the seeds may be their energy utilization. In this study, torrefaction was proposed as a method for the valorization of exotic fruit seeds (mango, lychee, avocado). Thus, the influence of torrefaction temperature (200–300 °C) on the physical-chemical properties of substrates was investigated. The obtained results revealed that, in relation to the unprocessed raw materials, the torreficates are characterized by improved hydrophobic properties (all materials are classified as extremely hydrophobic), higher heating value (at 300 °C the values increased from 17,789 to 24,842 kJ∙kg−1 for mango, from 18,582 to 26,513 kJ∙kg−1 for avocado, and from 18,584 to 25,241 kJ∙kg−1 for lychee), higher fixed carbon content (which changed from 7.87–15.38% to 20.74–32.47%), and significant mass loss, by 50–60%. However, as a side effect of thermal treatment, an increase in ash content (approx. 2–3 times but still less than in coal) was observed. Therefore, the torreficates may be competitive with coal. The possibility of using residues from the food processing sector as a substrate for energy purposes is important from the point of view of environment protection and is a part of the functioning of the circular economy.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.
hi@scite.ai
10624 S. Eastern Ave., Ste. A-614
Henderson, NV 89052, USA
Copyright © 2024 scite LLC. All rights reserved.
Made with 💙 for researchers
Part of the Research Solutions Family.