Magnetization process and adiabatic demagnetization of the antiferromagnetic Ising spin clusters with the shape of regular polyhedra (Platonic solids) are exactly examined within the framework of a simple graph-theoretical approach. While the Ising cube as the only unfrustrated (bipartite) spin cluster shows just one trivial plateau at zero magnetization, the other regular Ising polyhedra (tetrahedron, octahedron, icosahedron and dodecahedron) additionally display either one or two intermediate plateaux at fractional values of the saturation magnetization. The nature of highly degenerate ground states emergent at intermediate plateaux owing to a geometric frustration is clarified. It is evidenced that the regular Ising polyhedra exhibit a giant magnetocaloric effect in a vicinity of magnetization jumps, whereas the Ising octahedron and dodecahedron belong to the most prominent geometrically frustrated spin clusters that enable an efficient low-temperature refrigeration by the process of adiabatic demagnetization.
ABSTRACT. The betweenness centrality of a vertex of a graph is the portion of the shortest paths between all pairs of vertices passing through a given vertex. We study upper bounds for this invariant and its relations to the diameter and average distance of a graph.
The specific heat of regular Ising polyhedra is investigated in detail as a function of temperature and magnetic field. It is shown that the regular Ising polyhedra display diverse double-peak temperature dependences of the specific heat whenever the magnetic field approaches a level-crossing field. The Schottky theory of a two-level system often provides a plausible explanation of a height and position of low-temperature peak, which emerges in the specific heat of a regular Ising polyhedron due to low-lying excitations from a ground state to a first-excited state. The height and position of Schottky-type maximum depends essentially on a relative degeneracy of the ground state and first-excited state, which are in general quite distinct in geometrically frustrated Ising spin clusters. Low-temperature variations of the specific heat with the magnetic field exhibit multipeak structure with two peaks (of generally different height) symmetrically placed around each level-crossing field.
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