A facile hydrothermal method was developed to synthesize boehmite nanorods with a length of 50-2000 nm, a diameter of 6-20 nm, and a preferential growth along [100] by treating the Al(OH)(3) gel in acidified sulfate solutions at 240 degrees C. Studies on the hydrothermal treatment of Al(OH)(3) gel in sulfate solutions showed that the morphology and the composition of the hydrothermal products were connected with the sulfate concentration and the pH of the hydrothermal solution. The aspect ratio of the boehmite nanorods increased to 300 as the initial H(2)SO(4) concentration increased to 0.043 mol x L(-1), whereas boehmite nanorods and (H(3)O)Al(3)(SO(4))(2)(OH)(6) cubic particles coexisted in the case of the initial H(2)SO(4) concentration > or = 0.054 mol x L (-1). Sole boehmite nanoflakes with a diameter of about 50 nm were formed under alkaline conditions (pH 10.5) despite the existence of the sulfate. The chemical and Raman analyses indicated that SO(4)(2-) in acidified solutions adsorbed on the boehmite surface via H-bonds. On the basis of the above results, the growth of boehmite along the [100] direction was attributed to the selective adsorption of SO(4) (2-) on the (010) and (001) planes of boehmite.
Magnesium borate hydroxide (MgBO2(OH)) nanowhiskers with a diameter of 20–50 nm and a length of 0.5–3 μm were synthesized via a facile hydrothermal route, using MgCl2·6H2O, H3BO3, and NaOH as the reactants. Mg7B4O13·7H2O with poor crystallinity was formed after coprecipitation of the reactant solutions at room temperature, the hydrothermal treatment of the slurry at 240 °C for 18 h led to the formation of uniform MgBO2(OH) nanowhiskers with high crystallinity and preferential growth direction along the (200) plane.
We investigate the optical property of bent ZnO nanowires ͑NWs͒ obtained by low energy argon ion milling. At room temperature, the bent NWs demonstrates an enhanced near band edge ultraviolet emission, while the deep level green emission is totally suppressed. Temperature dependent photoluminescence measurements were carried out between 10 and 300 K for both the as-grown and the bent ZnO NWs. It is found that the emission peak energy of the bent NWs systematically shifts to lower energy compared to the as-grown NWs in the whole measured temperature range. Our results indicate that the redshift in the emission peak is related to the uniaxial tensile strain and the enhanced exciton-phonon coupling strength in the bent ZnO NWs.
Since the reform and opening up, Chinese economic and social development has undergone great changes, and the people’s living standards have improved markedly. For the national economy, the engineering construction is not only a carrier for specific economic tasks, but also a driving force for rapid and sustained economic development. With the continuous expansion of the scale of construction projects, safety management problems of construction projects are constantly exposed. How to effectively avoid accidents has become an important issue to be solved urgently in the construction industry. This paper mainly evaluates human factors in the process of construction project management, such as workers’ proficiency, workers’ safety awareness, technical workers’ quality, and workers’ emergency capacity, with the purpose of helping China’s construction projects proceed smoothly. In this research, we provide a multiple attribute group decision-making (MAGDM) technique based on Pythagorean 2-tuple linguistic numbers (P2TLNs) and the VIseKriterijumska Optimizacija I KOmpromisno Resenje (VIKOR) method for evaluating the human factors of construction projects. P2TLNs are used to represent the performance assessments of decision makers. Relying on a P2TLWA operator, P2TLWG operator, and the essential VIKOR method, a general framework is established. An application is presented to test the validity of the new method, and a comparative analysis with two algorithms and the P2TL-TODIM method is illustrated with detail.
Supplier selection in medical instrument industries is a classical multiple attribute group decision making (MAGDM) problem. The Pythagorean 2-tuple linguistic sets (P2TLSs) can reflect uncertain or fuzzy information well and solve the supplier selection in medical instrument industries, and the original Taxonomy is very appropriate for comparing different alternatives with respect to their advantages from studied attributes. In this study, we present an algorithm that combines Pythagorean 2-tuple linguistic numbers (P2TLNs) with the Taxonomy method, where P2TLNs are applied to express the evaluation of decision makers on alternatives. Relying on the Pythagorean 2-tuple linguistic weighted average (P2TLWA) operator or Pythagorean 2-tuple linguistic weighted geometric (P2TLWG) operator to fuse P2TLNs, the new general framework is established for Pythagorean 2-tuple linguistic multiple attribute group decision making (MAGDM) under the classical Taxonomy method. Ultimately, an application case for supplier selection in medical instrument industries is designed to test the novel method’s applicability and practicality and a comparative analysis with three other methods is used to elaborate further.
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