Atomically thin transition metal dichalcogenide crystals (TMDCs) have extraordinary optical properties that make them attractive for future optoelectronic applications. Integration of TMDCs into practical all‐dielectric heterostructures hinges on the ability to passivate and protect them against necessary fabrication steps on large scales. Despite its limited scalability, encapsulation of TMDCs in hexagonal boron nitride (hBN) currently has no viable alternative for achieving high performance of the final device. Here, it is shown that the novel, ultrathin Ga2O3 glass is an ideal centimeter‐scale coating material that enhances optical performance of the monolayers and protects them against further material deposition. In particular, Ga2O3 capping of monolayer WS2 outperforms commercial‐grade hBN in both scalability and optical performance at room temperature. These properties make Ga2O3 highly suitable for large‐scale passivation and protection of monolayer TMDCs in functional heterostructures.
Monolayer transition metal dichalcogenide crystals (TMDCs) hold great promise for semiconductor optoelectronics because their bound electron-hole pairs (excitons) are stable at room temperature and interact strongly with light. When TMDCs are embedded in an optical microcavity, excitons can hybridise with cavity photons to form exciton polaritons, which inherit useful properties from their constituents. The ability to manipulate and trap polaritons on a microchip is critical for applications. Here, we create a non-trivial potential landscape for polaritons in monolayer WS2, and demonstrate their trapping and ballistic propagation across tens of micrometers. We show that the effects of dielectric disorder, which restrict the diffusion of WS2 excitons and broaden their spectral resonance, are dramatically reduced for polaritons, leading to motional narrowing and preserved partial coherence. Linewidth narrowing and coherence are further enhanced in the trap. Our results demonstrate the possibility of long-range dissipationless transport and efficient trapping of TMDC polaritons in ambient conditions.
Dispersion engineering is a powerful and versatile tool that can vary the speed of light signals and induce negative-mass effects in the dynamics of particles and quasiparticles. Here, we show that dissipative coupling between bound electron-hole pairs (excitons) and photons in an optical microcavity can lead to the formation of exciton polaritons with an inverted dispersion of the lower polariton branch and hence, a negative mass. We perform direct measurements of the anomalous dispersion in atomically thin (monolayer) WS2 crystals embedded in planar microcavities and demonstrate that the propagation direction of the negative-mass polaritons is opposite to their momentum. Our study introduces the concept of non-Hermitian dispersion engineering for exciton polaritons and opens a pathway for realising new phases of quantum matter in a solid state.
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