To create life‐like movements, living muscle actuator technologies have borrowed inspiration from biomimetic concepts in developing bioinspired robots. Here, the development of a bioinspired soft robotics system, with integrated self‐actuating cardiac muscles on a hierarchically structured scaffold with flexible gold microelectrodes is reported. Inspired by the movement of living organisms, a batoid‐fish‐shaped substrate is designed and reported, which is composed of two micropatterned hydrogel layers. The first layer is a poly(ethylene glycol) hydrogel substrate, which provides a mechanically stable structure for the robot, followed by a layer of gelatin methacryloyl embedded with carbon nanotubes, which serves as a cell culture substrate, to create the actuation component for the soft body robot. In addition, flexible Au microelectrodes are embedded into the biomimetic scaffold, which not only enhance the mechanical integrity of the device, but also increase its electrical conductivity. After culturing and maturation of cardiomyocytes on the biomimetic scaffold, they show excellent myofiber organization and provide self‐actuating motions aligned with the direction of the contractile force of the cells. The Au microelectrodes placed below the cell layer further provide localized electrical stimulation and control of the beating behavior of the bioinspired soft robot.
As a promising alternative to traditional prepreg, carbon fiber/poly(ether ether ketone) (CF/PEEK) hybrid composites have attracted wide public interest for their flexibility and conformability. However, modification methods focused on the hybrid premix have not been previously studied. In the present work, the interfacial strength of the hybrid composite was improved by treating the carbon and PEEK fibers together in a radiofrequency (RF) plasma containing one of the following gases to achieve surface activation: air, Ar, or Ar–air. After plasma treatment, the increased roughness of CF and the grafted chemical groups of CFs and PEEK fibers were propitious to the mechanical interlocking and interfacial strength. Significant interfacial shear strength (IFSS) enhancement was achieved after Ar 1 min, air 1 min plasma treatment. This study offers an alternative method for improving the interfacial properties of CF/PEEK composites by focusing on the boundary layer and modifying and controlling the fiber–matrix interface.
Studies on carbon fiber (CF)/poly(ether ether ketone) (PEEK) fiber hybrid textiles were initiated several decades ago because their flexibility and conformability make them a promising alternative to traditional prepregs. The adhesion between the CFs and PEEK is mostly controlled by their inherent surface properties and mutual wettability. However, details of these properties remain largely unknown, especially those of PEEK. Therefore, to determine the surface and interfacial properties of these fibers, we performed a comprehensive study and characterized their surface topography (atomic force microscopy, scanning electron microscopy), surface chemistry [X-ray photoelectron spectrometry (XPS), acid–base titration], surface energies (wetting tests, acid–base approach), and interfacial mechanical properties [droplet test, interfacial shear strength (IFSS)]. These experiments were complemented by a theoretical approach to the prediction of the surface energy components (parachor) and contact angles of PEEK. We found good agreement between the results obtained by XPS and wetting tests (base-to-acid surface energy component ratio), as well as between the predicted and measured surface energy and contact angles. The results highlight the consistency and reliability of the proposed methodology. We found that both CFs and PEEK fibers appear to be smooth at the nanoscale and have large dispersive and basic surface energy components. The IFSS of CF/PEEK is significantly higher (44.87 ± 5.76 MPa) compared to that of other thermoplastic systems. The findings not only demonstrate the potential of CF/PEEK hybrid textiles but also emphasize the need to further increase the compatibility between CFs and PEEK fibers by increasing the acidic component of CF surfaces. Surface treatments and the design of a suitable sizing are potential methods to achieve this objective in future studies.
Stimuli-responsive porous polymer materials have promising biomedical application due to their ability to trap and release biomacromolecules. In this work, a class of highly porous electrospun fibers is designed using polylactide as the polymer matrix and poly(ethylene oxide) as a porogen. Carbon nanotubes (CNTs) with different concentrations are further impregnated onto the fibers to achieve self-sealing functionality induced by photothermal conversion upon light irradiation. The fibers with 0.4 mg mL−1 of CNTs exhibit the optimum encapsulation efficiency of model biomacromolecules such as dextran, bovine serum albumin, and nucleic acids, although their photothermal conversion ability is slightly lower than the fibers with 0.8 mg mL−1 of CNTs. Interestingly, reversible reopening of the surface pores is accomplished with the degradation of PLA, affording a further possibility for sustained release of biomacromolecules after encapsulation. Effects of CNT loading on fiber morphology, structure, thermal/mechanical properties, degradation, and cell viability are also investigated. This novel class of porous electrospun fibers with self-sealing capability has great potential to serve as an enabling strategy for trapping/release of biomacromolecules with promising applications in, for example, preventing inflammatory diseases by scavenging cytokines from interstitial body fluids.
Perovskite nanocrystals (PNCs) are promising candidates for solar‐to‐fuel conversions yet exhibit low photocatalytic activities mainly due to serious recombination of photogenerated charge carriers. Constructing heterojunction is regarded as an effective method to promote the separation of charge carriers in PNCs. However, the low interfacial quality and non‐directional charge transfer in heterojunction lead to low charge transfer efficiency. Herein, a CsPbBr3–CdZnS heterojunction is designed and prepared via an in situ hot‐injection method for photocatalytic CO2 reduction. It is found that the high‐quality interface in heterojunction and anisotropic charge transfer of CdZnS nanorods (NRs) enable efficient spatial separation of charge carriers in CsPbBr3–CdZnS heterojunction. The CsPbBr3–CdZnS heterojunction achieves a higher CO yield (55.8 µmol g−1 h−1) than that of the pristine CsPbBr3 NCs (13.9 µmol g−1 h−1). Furthermore, spectroscopic experiments and density functional theory (DFT) simulations further confirm that the suppressed recombination of charge carriers and lowered energy barrier for CO2 reduction contribute to the improved photocatalytic activity of the CsPbBr3–CdZnS heterojunction. This work demonstrates a valid method to construct high‐quality heterojunction with directional charge transfer for photocatalytic CO2 reduction. This study is expected to pave a new avenue to design perovskite–chalcogenide heterojunction.
Continuous carbon fiber (CF)-reinforced poly (ether ether ketone) (PEEK) composites have excellent mechanical properties, but their processing techniques are limited. Therefore, we promoted a braiding method based on the hybrid fiber method by hot-compacting CF/PEEK plain weave fabrics to solve the problem of difficult wetting between CF and PEEK. Four parameters—melting temperature, molding pressure, crystallization temperature and the resin contents—were investigated for optimized fabrication. After studying the melting range, thermal stability and the contact angle of PEEK under different temperatures, the melting temperature was set at 370 °C. An ultra-depth-of-field 3D microscope was adopted to investigate the effects of molding pressure in the melting stage. The tensile strength or modulus along and perpendicular to the carbon fiber direction and crystallinity under different crystallization temperatures were analyzed. As a result, the sample crystalized at 300 °C showed an excellent tensile properties and crystallinity. The increased mass ratio of PEEK ranging from 50.45% to 59.07% allowed for much stronger interfacial strength; however, the higher resin content can lead to the dispersion of CFs, loss of resin and the formation of defects during processing. Finally, the optimal resin mass content was 59.07%, with a tensile strength of 738.36 ± 14.49 MPa and a flexural strength of 659.68 ± 57.53 MPa. This paper studied the optimized processing parameters to obtain better properties from CF/PEEK plain weave fabrics and to further broaden the specific applications of CF/PEEK composites, demonstrating a new direction for its fabrication.
The design and development of thermal insulation materials is very important for the treatment of offshore oil pipelines. Understanding thermal energy transport in thermal insulation materials and predicting their thermal conductivities have important theoretical and practical value for the design of thermal insulation materials. In this work, lightweight and thermally insulated (LWTI) composites with the desired mechanical strength for offshore oil pipelines applications were prepared using epoxy resin (EP) as the matrix and hollow glass microspheres (HGMs) as the filler. The morphology, density, and mechanical properties of HGM/EP LWTI composites were studied first. The flexural strength and the flexural modulus of HGM/EP LWTI composites could still be as high as 22.34 ± 2.75 Mpa and 1.34 ± 0.03 GPa, respectively, while the density was only 0.591 g/cm3. The relationship between the effective thermal conductivity of HGM/EP LWTI composites and material parameters (sizes and contents together) has been studied systematically. A three-phase prediction model was built using the self-consistent approximation method to predict the effective thermal conductivity of HGM/EP LWTI composites, and the resin matrix, the wall thickness, the HGM particle size, and other parameters (such as air) were fully considered during the derivation of this three-phase thermal conductivity model. Finally, the insulation mechanism of HGM/EP LWTI composites was systematically analyzed. The thermal conductivities of HGM/EP LWTI composites with different diameters and HGM contents calculated by the three-phase prediction model agreed well with the experimental test results, with a minimum error of only 0.69%. Thus, this three-phase thermal conductivity model can be used to theoretically simulate the thermal conductivity of epoxy resin-based LWTI composites and can be the theoretical basis for the design and prediction of the thermal conductivity of other similar hollow spheres filled materials.
Supporting Information. The Supporting Information is available free of charge on the ACS Publications website at DOI: The SEM and TEM images of well dispersed HA/SWCNT solutions with 7 mg/mL SWCNTs; Chemical modification sites in HA and the schematic representations of HA crosslinked with HMDA after activation using EDC and HOBt; FTIR spectra of SWCNTs, uncrosslinked and crosslinked HA/SWCNT microfibers; 3D topography of uncrosslinked and crosslinked HA/CNTs microfiebrs with 7 mg/mL SWCNT concentration obtained using AFM; Tensile strength of uncrosslinked and crosslinked swollen HA/SWCNT microfibers as a function of SWCNT concentration; Failure strain of uncrosslinked and crosslinked swollen HA/SWCNT microfibers as a function of SWCNT concentration; SEM images of well dispersed HA/SWCNT solutions with 4 mg/mL and 7 mg/mL SWCNTs; Micrographs and SEM of HA/SWCNT dispersion with different SWCNT concentrations; Schematic illustration of the HA/SWCNT microfibers on the paper frame with different bending angles; Schematic illustration of the specimen (bottom), photographs of the fibers being tested in a tensile tester at rest (left) and maximum strain (right), and the corresponding load-displacement curve (middle); Cyclic voltammetry outcome of the HA/SWCNT microfibers with 7 mg/mL SWCNT concentration: current vs. scan rate; Viability of NIH-3T3 fibroblasts after five days of culture on the surface of HA/SWCNT microfibers with 7 mg/mL SWCNT concentration; The authors declare no competing financial interest.
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