An electrocatalyzed three-component cascade reaction of CO2, amines, and N-alkenylsulfonamides is developed, providing an environmentally friendly and efficient method of synthesizing a series of new carbamate compounds. This reaction meets...
3,4-dihydroquinolone is an important drug and biological compound molecule. o-halophenylacrylamides were cyclized by two-electron reduction under electrochemical catalysis to obtain the corresponding 3,4-dihydroquinolinone products. This electrochemical cyclization improves the selectivity...
In this review, recent progress in applying of CO2 as an electrophilic reagent and nitrogen as a nucleophilic center in organic synthesis is summarized. The used catalytic methods in the...
N-heterocyclic carbene and related complexes are a class of catalysts with excellent catalytic activity which are widely used in the chemical fixation of carbon dioxide. This review focuses on the application of a carbene-metal catalytic system, carbene-free-metal catalytic system and synergistic catalytic technology of various technologies in the conversion of carbon dioxide. The possible role of carbene materials in chemical carbon fixation is discussed by analyzing several types of typical chemical carbon fixation mechanisms.
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