16The photooxidative stability of an aromatic segmented poly(urethane-urea) (PUU) elastomer, 17 stabilised with a range of carbon black fillers, was assessed after very low UVA doses as a means to 18 identify components that are highly susceptible to UV degradation, and suggest better design of such 19 materials. Fourier-transform infrared (FTIR) analysis indicated rapid degradation of the urea bonds 20 in the hard segments, followed by chain scission and photo-Fries reaction of the urethane linkages. In 21 the soft segments, the oxidation of the original ether groups resulted in the formation of large 22 amounts of ester groups, while some crosslinking of the ether groups was also evident. Carbon black 23 provided moderate protection against degradation, with the smallest-sized particles being the most 24 effective. Protection was evidenced by reduced surface cracking as well as an increased resistance to 25 chemical changes in both the soft segments and hard segments. Even so, significant degradation was 26 still evident at low UV doses suggesting that further stabilisation is required to increase the UV 27 durability of these elastomers and improve their long-term performance. 28 29 Keywords: UV ageing; aromatic poly(urethane-urea); carbon black 30 system. PUUs have been found to exhibit better photostability than their polyurea counterparts [19]. 53However, due to limited work in this area, a complete description of the PUU photodegradation 54 process and how the UV irradiation affects the properties of PUU remain unclear. 55 effects of three types of carbon black with different structural characteristics on the UV stability of 77 this PUU were also studied. The photodegradation processes were analysed using Fourier-transform 78 infrared (FTIR) studies of the PUU surface chemistry over the monitoring period, along with other 79 techniques such as scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), 80 119 2.3 Accelerated UV ageing 120 Samples were cut from 2.5-3.5 mm thick flat sheets and loaded into custom-built extensometers 121 according to ASTM D1149-16 using Method B, Procedure B1 -Straight Specimens (Static 122 Elongation). The accelerated ageing method was adapted from UV Resistance MIL-STD-810G, 123Method 505.5, Procedure II (A2). Briefly, samples were loaded into a QUV accelerated weathering 124 tester (Q-Lab, Ohio, USA) that was equipped with UVA-340 lamps. The samples were held at 50°C 125 143 X-ray photoelectron spectroscopy (XPS) 144Surface analysis was performed on a Kratos Axis ULTRA X-ray photoelectron spectrometer 145 (XPS) using monochromatic Al Kα (hν = 1486.6 eV) radiation. Curve fitting was undertaken using a 146Gaussian-Lorentzian peak shape and Shirley background function. The binding energy was poly (etherurethane urea)
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