The preparation of biodegradable polymer foams with a stable high volume-expansion ratio (VER) is challenging. For example, poly (butylene adipate-co-terephthalate) (PBAT) foams have a low melt strength and high shrinkage. In this study, polylactic acid (PLA), which has a high VER and crystallinity, was added to PBAT to reduce shrinkage during the supercritical molded-bead foaming process. The epoxy chain extender ADR4368 was used both as a chain extender and a compatibilizer to mitigate the linear chain structure and incompatibility and improve the foamability of PBAT. The branched-chain structure increased the energy-storage modulus (G’) and complex viscosity (η*), which are the key factors for the growth of cells, by 1–2 orders of magnitude. Subsequently, we innovatively used the CO2 and N2 composite gas method. The foam-shrinkage performance was further inhibited; the final foam had a VER of 23.39 and a stable cell was obtained. Finally, after steam forming, the results showed that the mechanical strength of the PBAT/PLA blended composite foam was considerably improved by the addition of PLA. The compressive strength (50%), bending strength, and fracture load by bending reached 270.23 kPa, 0.36 MPa, and 23.32 N, respectively. This study provides a potential strategy for the development of PBAT-based foam packaging materials with stable cell structure, high VER, and excellent mechanical strength.
ZnO quantum dots sensitized SnO2 porous nanowires were fabricated and designed for UV excitation gas sensor. The ZnO/SnO2 composite (SZQ1%) with the molar proportion of 1:100 exhibits excellent sensing properties to NO2 gas under UV irradiation at 40oC. The humidity stability of SZQ1% was also measured and discussed by DC reversed circuit and complex impedance curves. The gas sensing mechanism is well discussed and illustrated to the ZnO quantum dots sensitized and the increased photo-generated carriers under UV irradiation.
LC-filter-based H6-bridge inverter (LC-H6) is a two-order inverter system, which is an appropriate circuit for the medium or high power inverter field. A novel discrete modeling technique with coefficient linearization based on stroboscopic map method is presented to reduce iterative computation and memory expense of the LC-filter-based H6-bridge inverter with PI controller (LCH6-PI) system. Meanwhile, the collision border lines of i are deduced. Then, based on the coefficient linear discrete model, stability regions of control parameter k
p, DC voltage E and load inductance L are analyzed. Finally, the simplified discrete model is verified by circuit simulation and experimental results. Stabilization analysis indicates that the stability boundary and chaos boundary can be obtained by period-doubling bifurcation and border collision, respectively.
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