Different approaches to master magnesia hydration in refractory castables have been recently proposed. Among them, the use of hydrating agents can change the Mg(OH) 2 crystals morphology and its distribution in the resultant microstructure, minimizing the drawbacks related to the reaction expansion. In this work, the hydrating effect of acetic acid in Al 2 O 3 -MgO cement-free castable properties during curing, drying, and firing steps was evaluated by elastic modulus, thermogravimetric, apparent porosity, and SEM analyses. Based on the attained results, adding acetic acid resulted in hydroxide crystals with distinct morphology and flexibility leading to a better accommodation of Mg(OH) 2 in the designed microstructure, which inhibited the samples' cracking during curing. In addition, the drying behavior of the evaluated compositions was further optimized by incorporating polypropylene fibers. Thus, this study highlights a novel perspective for fine MgO powders application, indicating that brucite morphology engineering may be a key aspect for the development of advanced Al 2 O 3 -MgO cement-free refractory castables. †
The açaí fruit depulping produces large amounts of long lignocellulosic fiber bundles that are disposed in the environment. Chemical pretreatments may improve açaí fibers favoring their usage in advanced materials. This work aimed to define optimal alkali reaction parameters to improve the properties of açaí fibers. Two NaOH concentrations (5 % and 10 %) and two reaction temperatures (80 °C and 100 °C) were tested. The raw and treated fibers were analyzed by scanning electron microscopy, Fourier transformed infrared spectroscopy, X‐ray diffraction, and thermal analyses. All the alkali pretreatments separated fibers from the bundles, unblocked pit channels by removing silicon structures, exposed the inner lignin, partially removed non‐cellulosic compounds, and raised the cellulose crystalline index. The highest temperature and NaOH content resulted in better cleaning and isolation of the fibers, while milder conditions better preserved the cellulose crystalline structure and thermal stability.
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