A New ligand, N-(2-oxo-1,2- Dihydropyrimidin-4- ylcarbamothioyl) Acetamide (DPA) was prepared by reaction of iso thiosyanate derivative with Cytosine. The ligand has been characterized through elemental analysis, H1 NMR, C13NMR, FT-IR, and UV Visible spectra, such ligand’s transition metal complexes have been characterized through conductivity measurement, FT-IR, UV Visible spectra and magnetic susceptibility, all the complexes of this ligand are solid crystal and molar ratio (2:1) (ligand: metal). The form of molecular for these complexes octa hedral. The general formula [M(DPA)2Cl2], where M+2 = (Mn, Co, Ni, Cu, Zn, Cd, Hg). Keywords: Cytosine, acetyl chloride, transition metals.
A new ligand 3-(3-acetylthioureido)propanoic acid (ATA) was prepared through the reaction of acetyl chloride, ammonium thiocyanate and b- alanine. For this study the following methods were used: FT-IR, 1H-NMR 13C-NMR spectra and the Elemental analysis. complexesis of M+2=Mn,Cu,Ni,Co,Zn,Cd and Hg derived from3-(3-acetylthioureido) propanoic acid have been synthesized and characterized by elemental analyses, molar conductance, magnetic suscpility, FT-IR, UV Vis spectra, The results have shown complexation with b-alanine derivative with metal ion in a 1:2 ratio. The spectral characterization confirms the formation of ligand and complexes. The evidences from the above results suggest the ligand to be abi dentate ion.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.