Increasing the areal capacity or electrode thickness in lithium ion batteries is one possible means to increase pack level energy density while simultaneously lowering cost. The physics that limit use of high areal capacity as a function of battery power to energy ratio are poorly understood and thus most currently produced automotive lithium ion cells utilize modest loadings to ensure long life over the vehicle battery operation. Here we show electrolyte transport limits the utilization of the positive electrode at critical C-rates during discharge; whereas, a combination of electrolyte transport and polarization lead to lithium plating in the graphite electrode during charge. Experimental measurements are compared with theoretical predictions based on concentrated solution and porous electrode theories. An analytical expression is derived to provide design criteria for long lived operation based on the physical properties of the electrode and electrolyte. Finally, a guideline is proposed that graphite cells should avoid charge current densities near or above 4 mA/cm 2 unless additional precautions have been made to avoid deleterious side reaction. Lithium-ion (Li-ion) batteries are currently being used as the primary energy storage device in hybrid, plug-in, and all electric vehicles. This commercialization has been possible only by leveraging decades of previous scientific and engineering advances on materials, electrodes, and cell development. However, interactions in this complex system are still not fully understood. Automotive grade battery cells are required to fulfill a variety of optimization criteria in order to meet customer expectations and enable highly functional, robust and competitive products. In Fig. 1, key cell level criteria are shown for available technology as well as future development goals. Many of these values are highly influential on each other. In order to optimize one of the criteria it is always necessary to critically evaluate the impact on others. Key goals are to increase vehicle range and decrease cost at the same time. Minimizing the fraction of non-active material is an intuitive path to achieve these goals; however, the cell power and rate capability must simultaneously be maintained. [1][2][3] To derive clear development goals, the high level targets can be broken down to specific component requirements on the different levels of a storage system. 1,4 In Fig. 2, an analysis is shown for a state of the art prismatic hard-case automotive cell format. A battery level specific energy of ∼225 Wh/kg is widely accepted to be a critical value for sustainable implementation of long range electric vehicles. It represents a useful ratio between vehicle weight and range. In order to achieve this high specific energy, all subcomponents of the storage system have to meet demanding requirements as well. On the cell level, large format cells are favorable as they reduce the amount of cell housing needed per cell volume. Prismatic cell formats have a positive influence on the packing densi...
Compound-layer microstructures obtained by gaseous nitriding and nitrocarburising treatments of α-Fe and Fe–N alloy and by subsequent treatments were analysed to obtain new information on the metastable Fe–N and Fe–N–C systems above 853 K at 1 atm. In the case of the binary Fe–N system, invariant temperatures and phase boundaries agree well with the literature data, only the γ/γ + γ' and the γ/γ + ∊ boundaries as determined in the present work by means of electron probe microanalysis are located at N contents up to 1 at.% lower than reported in previous works. In the case of the ternary Fe–N–C system, the invariant eutectoid reaction was found to occur in the range 853 K – 863 K, whereas the invariant transition reaction was found to occur in the range 868 K – 873 K. The obtained data were used to draw isothermal sections of the Fe–N–C system for 853 K and 893 K. The determined temperatures for the invariant eutectoid and transition reactions as well as the extent of the ternary ∊-phase field were compared with phase diagrams calculated on the basis of different thermodynamic descriptions of the Fe–N–C system.
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