Abstract. Understanding and controlling vibrations in condensed matter is emerging as an essential necessity both at fundamental level and for the development of a broad variety of technological applications. Intelligent design of the band structure and transport properties of phonons at the nanoscale and of their interactions with electrons and photons impact the efficiency of nanoelectronic systems and thermoelectric materials, permit the exploration of quantum phenomena with micro-and nanoscale resonators, and provide new tools for spectroscopy and imaging. In this colloquium we assess the state of the art of nanophononics, describing the recent achievements and the open challenges in nanoscale heat transport, coherent phonon generation and exploitation, and in nano-and optomechanics. We also underline the links among the diverse communities involved in the study of nanoscale phonons, pointing out the common goals and opportunities.

Insight into the mechanical behaviour of nanomaterials under the extreme condition of very high deformation rates and to very large strains is needed to provide improved understanding for the development of new protective materials. Applications include protection against bullets for body armour, micrometeorites for satellites, and high-speed particle impact for jet engine turbine blades. Here we use a microscopic ballistic test to report the responses of periodic glassy-rubbery layered block-copolymer nanostructures to impact from hypervelocity micron-sized silica spheres. Entire deformation fields are experimentally visualized at an exceptionally high resolution (below 10 nm) and we discover how the microstructure dissipates the impact energy via layer kinking, layer compression, extreme chain conformational flattening, domain fragmentation and segmental mixing to form a liquid phase. Orientation-dependent experiments show that the dissipation can be enhanced by 30% by proper orientation of the layers.

It is shown theoretically that a single acoustic pulse, a few picoseconds long, can reverse magnetization in a magnetostrictive material Terfenol-D. Following giant magnetoelastic changes of free energy density, the magnetization vector is ejected from a local in-plane energy minimum and decays into another minimum. For an acoustic pulse duration significantly shorter than magnetization precession period τac≪Tprec, the switching threshold is determined by the acoustic pulse area, i.e., pulse integral in the time domain, similar to coherent phenomena in optics. Simulation results are summarized in a magnetoacoustic switching diagram and discussed in the context of all-optical magnetization switching by circularly polarized light pulses.

This paper presents and discusses the temperature and frequency dependence of the longitudinal and shear viscoelastic response at MHz and GHz frequencies of the intermediate glass former glycerol and the fragile glass former tetramethyl-tetraphenyl-trisiloxane (DC704). Measurements were performed using the recently developed time-domain Brillouin scattering technique, in which acoustic waves are generated optically, propagated through nm thin liquid layers of different thicknesses, and detected optically after transmission into a transparent detection substrate. This allows for a determination of the frequency dependence of the speed of sound and the sound-wave attenuation. When the data are converted into mechanical moduli, a linear relationship between longitudinal and shear acoustic moduli is revealed, which is consistent with the generalized Cauchy relation. In glycerol, the temperature dependence of the shear acoustic relaxation time agrees well with literature data for dielectric measurements. In DC704, combining the new data with data from measurements obtained previously by piezo-ceramic transducers yields figures showing the longitudinal and shear sound velocities at frequencies from mHz to GHz over an extended range of temperatures. The shoving model's prediction for the relaxation time's temperature dependence is fairly well obeyed for both liquids as demonstrated from a plot with no adjustable parameters. Finally, we show that for both liquids the instantaneous shear modulus follows an exponential temperature dependence to a good approximation, as predicted by Granato's interstitialcy model.

Hypersound generation and detection by laser pulses incident on the interface of an opaque anisotropic crystal are theoretically and experimentally investigated in the case where the symmetry is broken by a tilt of its axis of symmetry relative to the interface normal. A nonlocal volumetric mechanism of plane shear sound excitation is revealed and a modification of the temporal shape of the reflectivity signal with variation in probe light polarization is observed, both attributed to asynchronous propagation of the acoustic eigenmodes. Experiments and theory demonstrate the possibility of using polycrystalline materials with an arbitrary distribution of grain orientations for the generation and the detection of picosecond shear ultrasound.

Using femtosecond laser pulses, coherent GHz acoustic phonons are efficiently photogenerated and photodetected in BiFeO3 (BFO) multiferroic single crystal. Due to the crystal lattice symmetry, longitudinal as well as two transverse acoustic modes are generated and detected, and the corresponding sound velocities are determined. This provides the opportunity to experimentally evaluate the elastic coefficients of the multiferroic compound BiFeO3 that have been estimated so far only through ab initio calculations. The knowledge of the elastic properties of BFO is highly desired for BFO integration in nanoelectronic devices. Moreover, our findings highlight also that BFO may be a good candidate for light-controlled coherent acoustic phonons sources.

Direct real-time visualization and measurement of laser-driven shock generation, propagation, and 2D focusing in a sample are demonstrated. A substantial increase of the pressure at the convergence of the cylindrical acoustic shock front is observed experimentally and simulated numerically. Single-shot acquisitions using a streak camera reveal that at the convergence of the shock wave in water the supersonic speed reaches Mach 6, corresponding to the multiple gigapascal pressure range ∼30 GPa.

Picosecond laser ultrasonic techniques for acoustic wave generation and detection have been employed to probe shear acoustic waves in liquid glycerol at gigahertz frequencies. The experimental approach uses a unique laser pulse shaping technique and a crystallographically canted metal layer to generate frequency-tunable transverse acoustic waves, and uses time-domain coherent Brillouin scattering to detect the waves after they propagate through a liquid layer and into a solid substrate. A linear frequency dependence is found for both the shear speed and attenuation rate in glycerol. DOI: 10.1103/PhysRevLett.102.107402 PACS numbers: 78.20.Hp, 43.35.+d, 78.40.Dw, 78.47.JÀ Fast structural relaxation dynamics in liquids continue to pose major fundamental challenges [1], in large measure because direct experimental access to key relaxing degrees of freedom over the time or frequency ranges of interest remains elusive. Both density and shear relaxation play central roles in the complex structural responses of viscoelastic materials. On slow time scales, dynamic mechanical analysis and sonic or related measurement methods can be used, while faster responses require measurements of longitudinal and shear acoustic waves in the megahertz and gigahertz frequency ranges. Much of the MHz range is now accessible to ultrasonics and impulsive stimulated thermal or Brillouin scattering (impulsive stimulated thermal or Brillouin scattering [2-5]), and (usually isolated) frequencies in the low GHz range may be accessed through spontaneous Brillouin scattering [6]. Recent work in x-ray Brillouin scattering has accessed THz longitudinal acoustic frequency ranges [7], but frequencies in the tens to hundreds of GHz range, where fast relaxation features occur, have remained difficult to access. Deep-UV Brillouin scattering from longitudinal acoustic waves in this range has been demonstrated [4,7], but its utility is limited by strong absorption in most materials. Picosecond ultrasonics [8], in which a short optical pulse generates a single-cycle acoustic pulse that is observed after propagation through a sample, has provided tabletop access to much of the GHz-frequency range for longitudinal acoustic waves. Adaptations of the method to enable GHz shear wave generation [9][10][11][12] have been developed. However, shear waves in liquids have remained elusive, to the extent that the challenges in ''seeking shear waves in liquids with picoseconds ultrasonics'' [13] have been elaborated explicitly. The use of multiple optical pulses to generate frequency-tunable, multiple-cycle longitudinal waves [14] has been demonstrated to improve acoustic spectral brightness for characterization of frequency-dependent material responses. Here we demonstrate this approach for generation of frequency-tunable shear as well as longitudinal acoustic waves in the GHz-frequency range. We further demonstrate a sample and optical configuration that permit the measurements to be conducted in viscoelastic liquids, whose GHz-frequency acoustic responses are of...