New difunctional methacrylate monomers containing f3 heteroatoms have been synthesized from o:-hydroxymethylacrylate esters or o:-chloromethylacryloyl chloride. These monomers are more reactive than their alkane counterparts (e.g., ethacrylates), giving polymers with molecular weights comparable to poly(itaconate)s. The simple synthetic approach described allows a wide range of difunctionalized acrylate monomers to be produced. Variations in both ester and ether substituents were explored for ease of synthesis and polymerization.
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