The Tore Supra tokamak is being transformed in an x-point divertor fusion device within the frame of the WEST (W-for tungsten-Environment in Steady-state Tokamak) project, launched in support to the ITER tungsten divertor strategy. The WEST project aims at testing W monoblock Plasma Facing Units (PFU) under long plasma discharge, with thermal loads of the same magnitude as those expected for ITER. The others Plasma Facing Components (PFC) will also be modified and coated with W to transform Tore Supra into a fully metallic environment. Different coating techniques have been selected, taking into account the specifications of the various PFC: heat loads, complex geometries (length up to 1m) and different substrates (CuCrZr for actively cooled PFC, graphite and CFC for other components). This paper gives an overview on the different processes used and the associated validation program and concludes on the adequacy of the W coating with the WEST experimental program requirements.
The present study describes the in-situ electrochemical modifications which affect irradiated PWR UO 2 fuels in the course of a power ramp, by means of in-situ oxido-reduction indicators such as chromium or neo-formed chemical phases. It is shown that sub-stoichiometric irradiated fuels under temperature gradient such as that occurring during high power transients are submitted to strong oxido-reduction perturbations, owing to radial migration of oxygen from the hot center to the cold periphery of the pellet. The oxygen redistribution, similar to that encountered in Sodium Fast Reactors fuels, induces a massive reduction/precipitation of the fission products Mo, Ru, Tc and Cr (if present) in the high temperature pellet section and the formation of highly oxidized neo-formed grey phases of U 4 O 9 type in its cold section, of lower temperature. To our knowledge, it is the first time that such a phenomenon, likely to greatly impact the corrosive fission gas release, is experimentally attested for PWR fuels. The parameters governing the oxidation states of UO 2 fuels under power ramps are finally debated from a cross-analysis of our results and other published information. The potential chemical benefits brought by oxido-reductive additives in UO 2 fuel such as chromium oxide, in connection with their oxygen buffering properties, are discussed.
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