The aim of this study is to prepare a two-dimensional (2D) WO 3 ·H 2 O nanostructure assembly into a flower shape with good chemical stability for electrochemical studies of catalyst and energy storage applications. The 2D-WO 3 ·H 2 O nanoflowers structure is created by a fast and simple process at room condition. This cost-effective and scalable technique to obtain 2D-WO 3 ·H 2 O nanoflowers illustrates two attractive applications of electrochemical capacitor with an excellent energy density value of 25.33 W h kg –1 for high power density value of 1600 W kg –1 and good hydrogen evolution reaction results (low overpotential of 290 mV at a current density of 10 mA cm –2 with a low Tafel slope of 131 mV dec –1 ). A hydrogen evolution reaction (HER) study of WO 3 in acidic media of 0.5 M H 2 SO 4 and electrochemical capacitor (supercapacitors) in 1 M Na 2 SO 4 aqueous electrolyte (three electrode system measurements) demonstrates highly desirable characteristics for practical applications. Our design for highly uniform 2D-WO 3 ·H 2 O as catalyst material for HER and active material for electrochemical capacitor studies offers an excellent foundation for design and improvement of electrochemical catalyst based on 2D-transition metal oxide materials.
The crystal structure, electronic structure, and diffusion mechanism of Na ions in the cathode material Na 2 Mn 3 (SO 4 ) 4 are investigated based on the Heyd−Scuseria−Ernzerhof hybrid density functional method. The simultaneous motion model of polaron−sodium vacancy complexes was used to reveal the diffusion mechanism of Na ions in this material. Polaron formation at the Mn third-nearest neighbor to the Na vacancy was found. Two crossing and two parallel elementary diffusion processes of the polaronNa vacancy complex were explored. The most preferable elementary diffusion process has an activation energy of 852 meV, which generates a zigzag-like pathway of Na-ion diffusion along the [001] direction in the whole material. Possessing a voltage of 4.4 V and an activation energy of 852 meV, Na 2 Mn 3 (SO 4 ) 4 is expected to be a good cathode material for rechargeable sodium ions.
Herein, for the first time, we present two-dimensional (2D) NH 4 V 3 O 8 nanoflakes as an excellent material for both energy conversion of the hydrogen evolution reaction and storage of supercapacitors by a simple and fast two-step synthesis, which exhibit a completely sheet-like morphology, high crystallinity, good specific surface area, and also stability, as determined by thermogravimetric analysis. The 2D-NH 4 V 3 O 8 flakes show an acceptable hydrogen evolution performance in 0.5 M H 2 SO 4 on a glassy carbon electrode (GCE) coated with 2D-NH 4 V 3 O 8 , which results in a low overpotential of 314 mV at −10 mA cm –2 with an excellent Tafel slope as low as 90 mV dec –1 . So far, with the main focus on energy storage, 2D-NH 4 V 3 O 8 nanoflakes were found to be ideal for supercapacitor electrodes. The NH 4 V 3 O 8 working electrode in 1 M Na 2 SO 4 shows an excellent electrochemical capability of 274 F g –1 at 0.5 A g –1 for a maximum energy density of 38 W h kg –1 at a power density as high as 250 W kg –1 . Moreover, the crystal structure of 2D-NH 4 V 3 O 8 is demonstrated by density functional theory (DFT) computational simulation using three functionals, GGA, GGA + U , and HSE06. The simple preparation, low cost, and abundance of the NH 4 V 3 O 8 material provide a promising candidate for not only energy conversion but also energy-storage applications.
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