In the past decades, the physicochemical properties of electron donor−acceptor, EDA, complexes (also called charge-transfer, CT, complexes) have been extensively studied, although their synthetic applications have been somewhat limited. However, in recent years, this scenario has started to change as an increasing number of examples have been reported. In this regard, this review aims to present and discuss the main aspects associated with the physicochemical properties of these complexes and a selection of synthetic photochemical applications in organic chemistry.
The upgrading of biomass‐derived compounds has arisen in recent years as a very promising research field in both academia and industry. In this sense, a lot of new processes and products have been developed, often involving levulinic acid as a starting material or intermediate. In the last few years, though, other scaffolds have been receiving growing attention, especially, angelica lactones. Considering these facts and the emergent applications of said molecules, in this review we will discuss their preparation and applications; the use of these frameworks as starting materials in organic synthesis to produce potential bioactive compounds will be covered, as will their use as a foundation to highly regarded compounds such as liquid alkanes with prospective use as fuels and polymers.
A magnetic ZSM-5 zeolite with a core–shell type structure was synthesized, fully characterized and had its catalytic activity evaluated on the valorization of bio-derived furfuryl alcohol.
An array of Pd, Fe and Ir exchanged β-zeolites were synthesized, fully characterized, and their catalytic activity evaluated in converting bio-derived compounds to value-added platform chemicals.
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