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Arsenic contamination of drinking water is a serious water quality problem in many parts of the world. In this study, a low-cost manganese oxide ore from Vietnam (Vietnamese manganese oxide (VMO)) was firstly evaluated for its performance in arsenate (As(V)) removal from water. This material contains both Mn (25.6%) and Fe (16.1%) mainly in the form of cryptomelane and goethite minerals. At the initial As(V) concentration of 0.5 mg/L, the adsorption capacity of original VMO determined using the Langmuir model was 0.11 mg/g. The modified VMOs produced by coating VMO with iron oxide (Fe a -VMO) and zirconium oxide (Zr a -VMO) at 110 °C and 550 °C achieved the highest As(V) adsorption capacity when compared to three other methods of VMO modifications. Langmuir maximum adsorption capacities of Fe a -VMO and Zr a -VMO at pH 7.0 were 2.19 mg/g and 1.94 mg/g, respectively, nearly twenty times higher than that of the original VMO. Batch equilibrium adsorption data fitted well to the Langmuir, Freundlich, and Temkin models and batch kinetics adsorption data to pseudo-first order, pseudo-second order, and Elovich models. The increase of pH progressively from 3 to 10 reduced As(V) adsorption with a maximum reduction of 50-60% at pH 10 for both original and modified VMOs. The co-existing oxyanions considerably weakened the As(V) removal efficiency because they competed with As(V) anions. The competition order was PO 4. The characteristics of the original and modified VMOs evaluated using SEM, FTIR, XRD, XRF, surface area, and zeta potential explained the As(V) adsorption behaviour.

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