The commercialization of electrochemical water splitting technology requires electrocatalysts that are cost‐effective, highly efficient, and stable. Herein, an advanced bifunctional electrocatalyst based on single‐atom Co‐decorated MoS2 nanosheets grown on 3D titanium nitride (TiN) nanorod arrays (CoSAs‐MoS2/TiN NRs) has been developed for overall water splitting in pH‐universal electrolytes. When applied as a self‐standing cathodic electrode, the CoSAs‐MoS2/TiN NRs requires overpotentials of 187.5, 131.9, and 203.4 mV to reach a HER current density of 10 mA cm–2 in acidic, alkaline, and neutral conditions, respectively, which are superior to the most previously reported non‐noble metal HER electrocatalysts at the same current density. The CoSAs‐MoS2/TiN NRs anodic electrode also shows low OER overpotentials of 454.9, 340.6, and 508.0 mV, respectively, at a current density of 10 mA cm–2 in acidic, alkaline, and neutral mediums, markedly outperforming current OER catalysts reported elsewhere. More importantly, an electrolyzer delivered from the cathodic and anodic CoSAs‐MoS2/TiN NRs electrodes exhibits an extraordinary overall water splitting performance with good stability and durability in pH‐universal conditions.
A novel hybrid of small core@shell structured CoSx@Cu2MoS4 uniformly hybridizing with a molybdenum dichalcogenide/N,S‐codoped graphene hetero‐network (CoSx@Cu2MoS4‐MoS2/NSG) is prepared by a facile route. It shows excellent performance toward the oxygen reduction reaction (ORR), oxygen evolution reaction (OER), and hydrogen evolution reaction (HER) in alkaline medium. The hybrid exhibits rapid kinetics for ORR with high electron transfer number of ≈3.97 and exciting durability superior to commercial Pt/C. It also demonstrates great potential with remarkable stability for HER and OER, requiring low overpotential of 118.1 and 351.4 mV, respectively, to reach a current density of 10 mA cm−2. An electrolyzer based on CoSx@Cu2MoS4‐MoS2/NSG produces low cell voltage of 1.60 V and long‐term stability, surpassing a device of Pt/C + RuO2/C. In addition, a Zn‐air battery using cathodic CoSx@Cu2MoS4‐MoS2/NSG catalyst delivers a high cell voltage of ≈1.44 V and a power density of 40 mW cm−2 at 58 mA cm−2, better than the state‐of‐the‐art Pt/C catalyst. These achievements are due to the rational combination of highly active core@shell CoSx@Cu2MoS4 with large‐area and high‐porosity MoS2/NSG to produce unique physicochemical properties with multi‐integrated active centers and synergistic effects. The outperformances of such catalyst suggest an advanced candidate for multielectrocatalysis applications in metal‐air batteries and hydrogen production.
Developing
efficient and cost-effective bifunctional electrocatalysts
for both oxygen reduction reaction (ORR) and oxygen evolution reaction
(OER) is highly important for fabricating energy conversion and storage
technologies, such as fuel cells, water electrolyzers, and metal–air
batteries. Herein, we report a facile and economical route for synthesizing
ultrasmall molybdenum phosphide (MoP
y
)
nanocrystal-attached mesoporous manganese phosphides on N,P-codoped
graphene nanosheets, which display equivalent ORR (OER) activity to
that of Pt/C (RuO2) catalysts. This is manifested by the
positive onset potential (0.969 V) and half-wave potential (0.842
V) for ORR, as well as a mere overpotential of 301 mV at a current
density of 20 mA·cm–2 and a small Tafel slope
of 105 mV·dec–1 for OER in alkaline medium.
It also demonstrates remarkable stability in comparison with Pt/C
and RuO2 for both ORR and OER, respectively. The excellent
performance can be attributed to the mesoporous structure with enhanced
multiple types of electroactive sites, which highly favors the adsorption
and catalyzation of reactants, as well as efficient reagent/product
mass transport. The findings can pave a new way for the synthesis
and usage of a hybrid as a bifunctional catalyst with high efficiency
and outstanding longevity to enable next generation of energy conversion
and storage.
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