Nanoscale light emitting diodes (nanoLEDs, diameter < 1 µm), with active and sacrificial multi-quantum well (MQW) layers epitaxially grown via metal organic chemical vapor deposition, were fabricated and released into solution using a combination of colloidal lithography and photoelectrochemical (PEC) etching of the sacrificial MQW layer. PEC etch conditions were optimized to minimize undercut roughness, and thus limit damage to the active MQW layer. NanoLED emission was blue-shifted ∼10 nm from as-grown (unpatterned) LED material, hinting at strain relaxation in the active InGaN MQW layer. X-ray diffraction also suggests that strain relaxation occurs upon nanopatterning, which likely results in less quantum confined Stark effect. Internal quantum efficiency of the lifted nanoLEDs was estimated at 29% by comparing photoluminescence at 292K and 14K. This work suggests that colloidal lithography, combined with chemical release, could be a viable route to produce solution-processable, high efficiency nanoscale light emitters.

Recent technological advancements have enabled strong light-matter interaction in highly dissipative cavity-emitter systems. However, in these systems, which are well described by the Tavis-Cummings model, the considerable loss rates render the realization of many desirable nonlinear effects, such as saturation and photon blockade, problematic. Here we present another effect occurring within the Tavis-Cummings model: a nonlinear response of the cavity for resonant external driving of intermediate strength, which makes use of large cavity dissipation rates. In this regime, (N + 1)-photon processes dominate when the cavity couples to N emitters. We explore and characterize this effect in detail, and provide a picture of how the effect occurs due to destructive interference between the emitter ensemble and the external drive. We find that a central condition for the observed effect is large cooperativity, i.e., the product of the cavity and emitter decay rates is much smaller than the collective cavity-emitter interaction strength squared. Importantly, this condition does not require strong coupling. We also find an analytical expression for the critical drive strength at which the effect appears. Our results have potential for quantum state engineering, e.g., photon filtering, and could be used for the characterization of cavity-emitter systems where the number of emitters is unknown. In particular, our results open the way for investigations of unique quantum-optics applications in a variety of platforms that neither require high-quality cavities nor strong coupling.