[a] 1IntroductionAf undamentalu nderstanding of the adhesionb etween explosives residues, swabs used during detection of these residues, and surfaces to which the residues adhere is necessary to optimize the detection of these residues in airport security settings. The basic forcest hat control the behavioro f the residues are the van der Waals (vdW)f orces, whichc an be considered to be comprised of Keesom (dipole-dipole interactions), Debye (dipole-induced dipole interactions), and London dispersion forces( induced dipole-induced dipole interactions). The Hamaker constant A estimates the magnitude of vdW forcesb etweent wo dissimilar materials or within ap ure material [1].A dhesive Hamaker constants betweenm aterials i and k in medium j are denoted as A ijk while cohesive Hamaker constants for material i in a vacuum are denoteda sA ii .U sing combining rules established by Israelachvili [1],f amilies of A ii can be used to estimate A ijk amongavariety of materials in varying media. As ar esult, A ii of explosivesr esidues allow prediction of A ijk 's (and correspondingly the strengtho fa dhesion) between these residues and commonly swabbed surfaces.Methods of predicting A ii using Hamaker's pair-wise additive approach [2]