Equilibrium constants of a fundamental reaction of the aluminium subhalide process, 2Al(l)+AlCl3(g)= this experiment, equilibrium constants and standard free energy were obtained by the following equation:The heat of formation and entropy of AlCl(g) obtained from the experimental data and other thermodynamic values were -22,250cal/mot and 48.7cal/mol respectively. By the use of the equilibrium constants, the reaction ratio of aluminium trichloride was calculated at a reduced pressure and in argon carrier, respectively.
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