The regions of Durham and York in Ontario, Canada have partnered to construct an energy-from-waste thermal treatment facility as part of a long term strategy for the management of their municipal solid waste. This paper presents the results of a comprehensive human health risk assessment for this facility. This assessment was based on extensive sampling of baseline environmental conditions (e.g., collection and analysis of air, soil, water, and biota samples) as well as detailed site specific modeling to predict facility-related emissions of 87 identified contaminants of potential concern. Emissions were estimated for both the approved initial operating design capacity of the facility (140,000 tonnes per year) and for the maximum design capacity (400,000 tonnes per year). For the 140,000 tonnes per year scenario, this assessment indicated that facility-related emissions are unlikely to cause adverse health risks to local residents, farmers, or other receptors (e.g., recreational users). For the 400,000 tonnes per year scenarios, slightly elevated risks were noted with respect to inhalation (hydrogen chloride) and infant consumption of breast milk (dioxins and furans), but only during predicted 'upset conditions' (i.e. facility start-up, shutdown, and loss of air pollution control) that represent unusual and/or transient occurrences. However, current provincial regulations require that additional environmental screening would be mandatory prior to expansion of the facility beyond the initial approved capacity (140,000 tonnes per year). Therefore, the potential risks due to upset conditions for the 400,000 tonnes per year scenario should be more closely investigated if future expansion is pursued.
This study established Ni phytotoxicity thresholds for oat (Avena sativa L.) in four soil types, each created by blending a low and a high Ni soil, to generate a range of concentrations. The first quartile effective concentration (EC25) for soil and shoot tissue Ni concentration and reduction in shoot dry weight (DW) was determined using a Weibull function. The EC25 (for soil Ni concentration) was 1350, 1950, 1880 and > 2400 mg Ni kg-1 soil, for sand, till clay, heavy clay and organic muck, respectively. The EC25 (for shoot Ni concentration) was 71, 21, 52 and > 35 mg Ni kg-1 shoot DW, for sand, till clay, heavy clay and organic muck, respectively. Total soil Ni concentration, soil pH and soil cation exchange capacity (CEC) accounted for 70% of the variation of Ni accumulation in tissue when the data for all four of the soils were combined; this was similar to the amount of variation accounted for by fitting Ni concentration in tissue to ammonium oxalate extractable soil Ni. Manganese deficiency may have impaired plant growth at higher soil Ni concentrations in the clay soils. Speciation of Ni was similar in all soils studied, and the relationship between Ni concentrations in soil and in tissue was less closely related to chemically extracted soil Ni than it was to a combination of total soil Ni, soil pH and CEC. These are the soil characteristics known to influence both equilibrium among metal species in soil solution, and uptake of cations by plants. Key words: Avena sativa L., EC25, Ni, oat
The objective of this study was to quantify consumption of clothianidin-treated corn seed by birds following standard planting practices. Based on post-planting seed counts on 21 fields in southwestern Ontario, Canada, between 29 and 813 seeds/ha (mean of 224 ± 167 (SD)) were estimated to remain on the soil surface immediately post planting (i.e., less than one seed per 10 m2). This represents between 0.03 and 1.2% of the total sown seeds. The number of seeds missing on each field on the third day after planting as a result of any process (e.g., removal by foraging birds or mammals or burial as a result of heavy rains) ranged from 0 to 136 seeds/ha (0 to 0.0136 seeds/m2). Behavior monitoring of individual birds and 24 h remote video surveillance were deployed to investigate how much of the treated seed remaining on the soil surface was consumed by birds. Spotting scopes were used to monitor the full duration of the field visits of 596 individual birds during morning hours for three consecutive days after planting on the 21 fields. Two birds were observed consuming treated seeds (one seed each) and three birds consumed seeds for which the treatment status could not be visually confirmed. Additionally, constant (24 h) video surveillance for 2–4 days immediately after planting was deployed at 24 areas where multiple treated seeds were found on the soil surface. Across 1,380 h of collected video footage (including both day and night periods), no birds were observed to consume any treated seeds. This study provides field evidence of two factors that determine exposure of birds to clothianidin-treated corn seeds: (1) standard sowing practices in Ontario are effective at burying treated seeds such that the proportion of sown seeds that remain on the soil surface after planting is low, and (2) birds monitored on these fields consumed very few of the clothianidin-treated corn seeds remaining on the soil surface after planting. As these results are dependent on planting techniques and seed characteristics, they are not necessarily applicable to other types of clothianidin treated seed.
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