The end-Triassic mass extinction event (ETE) is considered to be linked with the emplacement of the Central Atlantic magmatic province (CAMP), yet their temporal relation and underlying nature of global environmental and biotic changes remain controversial. A drastic radiolarian faunal turnover was associated with deep-sea acidification and changes in the chemical composition of pelagic terrigenous components, which were interpreted as the results of increased CAMP-derived materials, such as Fe2O3/Al2O3, MgO/Al2O3, and SiO2/Al2O3, without statistical tests. Here, we re-examined these CAMP-like signatures in terms of changes in the chemical composition of the Triassic–Jurassic pelagic deep-sea chert succession in Japan. Our newly compiled dataset suggests that changes in Fe2O3/Al2O3 and MgO/Al2O3 across the ETE were not significant, and thus, they may not be appropriate proxies for CAMP-derived material, potentially due to the dissolution of iron by ocean acidification and the formation of chlorite during diagenesis, respectively. Decreased SiO2/Al2O3 was also considered to have been reflected in increased CAMP-related dust flux and/or decreased biosiliceous productivity, but a slight increase in the Al2O3/TiO2 ratio (a biosiliceous productivity proxy) and an increase in shale bed thickness (dust flux proxy) across the radiolarian ETE imply increased eolian dust flux rather than decreased productivity. Furthermore, statistically significant Na enrichment at the radiolarian ETE level might be related to CAMP volcanism and/or associated changes in the source areas of eolian dust.
In the Late Triassic, a global environmental change called the Carnian Pluvial Episode (CPE) emerged, causing major biological turnover. The CPE has been recognized by siliciclastic input to sedimentary basins, multiple carbon isotope perturbations, and climate proxies for humidification. The CPE is considered to have been associated with increased atmospheric pCO2 from eruptions of large igneous provinces. However, the nature of this global environmental perturbation on the continents is still not well understood. Here we present a geochemical analysis of a pelagic deep-sea bedded chert sequence across the CPE in the Jurassic accretionary complex of Mino terrane, central Japan. Fluctuations in terrigenous material supply were reconstructed using Principal Component Analysis of major element compositions. The first principal component positively correlates with elements enriched in clay minerals such as Al2O3, whereas it negatively correlates with CaO, P2O5, and MnO, derived from apatite and manganese. A sudden increase in terrigenous supply was detected around the Julian/Tuvalian boundary, suggesting that CPE-related siliciclastic input also occurred in the abyssal plain environment. The terrigenous supply returned to the pre-CPE state in the Tuvalian. Since the terrigenous material supplied to the abyssal plain is thought to be derived from eolian dust blown from continental arid regions, the increasing terrigenous supply detected in the pelagic deep-sea chert succession may indicate extensive aridification. This result seems to conflict with the common view of the CPE as a humidification event. This contradiction possibly suggests that the extensive aridification occurred within the interior of the supercontinent Pangea, while hydrological circulation enhanced on the coastal region during the CPE.
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