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We present results and a method to geophysically image the subsurface structures of maar volcanoes to better understand eruption mechanisms and risks associated with maar-forming eruptions. High-resolution ground gravity and magnetic data were acquired across several maar volcanoes within the Newer Volcanics Province of southeastern Australia, including the Ecklin maar, Red Rock Volcanic Complex, and Mount Leura Volcanic Complex. The depth and geometry of subsurface volcanic structures were determined by interpretation of gridded geophysical data and constrained 2.5-D forward and 3-D inverse modeling techniques. Bouguer gravity lows identified across the volcanic craters reflect lower density lake sediments and pyroclastic debris infilling the underlying maar-diatremes. These anomalies were reproduced during modeling by shallow coalesced diatremes. Short-wavelength positive gravity and magnetic anomalies identified within the center of the craters suggest complex internal structures. Modeling identified feeder vents, consisting of higher proportions of volcanic debris, intrusive dikes, and ponded magma. Because potential field models are nonunique, sensitivity analyses were undertaken to understand where uncertainty lies in the interpretations, and how the models may vary between the bounds of the constraints. Rather than producing a single "ideal" model, multiple models consistent with available geologic information are created using different inversion techniques. The modeling technique we present focuses on maar volcanoes, but there are wider implications for imaging the subsurface of other volcanic systems such as kimberlite pipes, scoria cones, tuff rings, and calderas.

The McArthur River (HYC) Zn-Pb-Ag deposit in the Carpentaria Zn belt, northern Australia, is one of the world’s largest and most studied sediment-hosted base metal deposits, owing to its lack of deformation and preservation of sedimentary and ore textures. However, the ore formation process (syngenetic vs. epigenetic) is still a subject of controversy. In this paper we focus on key characteristics of the HYC deposit that remain unexplained: preservation of sedimentary carbonate (dolomite) and its association with Zn, and the role of thallium (Tl) and manganese (Mn) distribution in the orebody. Our findings demonstrate a sequence of events during ore formation: Tl is hosted almost exclusively within euhedral pyritic overgrowths around early diagenetic pyrite; sphalerite mineralization occurred after Tl-bearing pyrite overgrowths, in association with acid dissolution (replacement) of laminated and nodular dolomite across the subbasin; and outer rims are enriched in Mn on preserved dolomite at the dissolution reaction front in contact with sphalerite. New thermodynamic fluid chemistry modeling demonstrates the metal distribution and paragenesis can be explained by acidic, oxidized ore fluids entering the pyrite-dolomite host lithology, allowing reduction and pH buffering by acid carbonate dissolution, resulting in stepwise metal deposition in an evolving fluid. We argue this represents strong evidence for epigenetic ore formation at HYC. Furthermore, the primary control on ore deposition is not synsedimentary faulting in the subbasin; rather, the chemical potential of sedimentary carbonate within reduced, sulfidic lithologies appears to be of critical importance to precipitation of sphalerite.

The Newer Volcanics Province of SE Australia is a very large continental basaltic province, with an area of >23 000 km2, a dense rock equivalent volume of <900 km3 and >400 monogenetic volcanoes; it has been active since c. 8 Ma. Lava fields, shields, scoria cones are common, and there are >40 maars and volcanic complexes. Maars occur dominantly in the south where magmas erupted through Tertiary sedimentary aquifers, whereas in the north, over Palaeozoic crust, there are few. Complex interactions of the magma volatile content, magma ascent rates, conduit characteristics and the availability and depth of aquifers caused diverse eruption styles. Volcanoes commonly occur close to major crustal faults, which acted as magma conduits. There is no simple age pattern of volcanism across the province. Volcanism was probably triggered by transtensional decompression in the crust where fault sets intersect, affecting hot, hydrated mantle that had welled up through edge-driven convection where the base of the lithosphere thins abruptly at the edge of the continent. Rock compositions range from picritic to basaltic andesitic. Some volcanoes are polymagmatic. Regional geophysical datasets have clarified the regional characteristics of the province, whereas detailed ground magnetic and gravity surveys resulted in new insights into the subsurface structure of maar-diatremes.

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