Tara P. Dasgupta scite author profile

The air-stable iridium chlorodihydride complex IrH2Cl[(iPr2PC2H4)2NH], 1, was prepared from the reaction of [IrCl(coe)2]2 with the pincer ligand (iPr2PC2H4)2NH in 2-propanol at 80 °C. Reaction of 1 with KOtBu in THF resulted in the formation of the air-sensitive amidodihydride complex IrH2[(iPr2PC2H4)2N], 2, which in the presence of 2-propanol readily forms the moderately air-stable trihydride complex IrH3[(iPr2PC2H4)2NH], 3. The trihydride and amidodihydride complexes in the absence of a base are exceptionally active catalysts for the transfer hydrogenation of ketones in 2-propanol.

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Kinetics and Mechanism of the Decomposition of S-Nitrosoglutathione by l-Ascorbic Acid and Copper Ions in Aqueous Solution to Produce Nitric Oxide

Smith

Dasgupta

2000

Nitric Oxide

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Dynamics of pesticides in tropical conditions. 1. Kinetic studies of volatilization, hydrolysis, and photolysis of dieldrin and .alpha.- and .beta.-endosulfan

Singh¹,

Dasgupta²,

Roberts³

et al. 1991

J. Agric. Food Chem.

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Kinetics and mechanism of aquation and formation reactions of carbonato complexes. V. Carbon dioxide uptake by hydroxopentaamminecobalt(III) ion to form carbonatopentaamminecobalt(III) ion

Chaffee¹,

Dasgupta²,

Harris³

1973

J. Am. Chem. Soc.

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Effects of S-Nitroso-N-acetyl-penicillamine Administration on Glucose Tolerance and Plasma Levels of Insulin and Glucagon in the Dog

2001

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Oxidation of biological substrates by chromium(VI). Part 1. Mechanism of the oxidation of L-ascorbic acid in aqueous solution

Dixon¹,

Sadler²,

Dasgupta³

1993

J. Chem. Soc., Dalton Trans.

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Acrylamide in Caribbean foods – Residual levels and their relation to reducing sugar and asparagine content

2012

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Mechanism of Nitric Oxide Release. I. Two-electron Reduction of Sodium Nitroprusside by l -cysteine in Aqueous Solution

Smith

Dasgupta

2002

Inorganic Reaction Mechanisms

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Tara P. Dasgupta

A Family of Active Iridium Catalysts for Transfer Hydrogenation of Ketones

Kinetics and Mechanism of the Decomposition of S-Nitrosoglutathione by l-Ascorbic Acid and Copper Ions in Aqueous Solution to Produce Nitric Oxide

Dynamics of pesticides in tropical conditions. 1. Kinetic studies of volatilization, hydrolysis, and photolysis of dieldrin and .alpha.- and .beta.-endosulfan

Kinetics and mechanism of aquation and formation reactions of carbonato complexes. V. Carbon dioxide uptake by hydroxopentaamminecobalt(III) ion to form carbonatopentaamminecobalt(III) ion

Effects of S-Nitroso-N-acetyl-penicillamine Administration on Glucose Tolerance and Plasma Levels of Insulin and Glucagon in the Dog

Oxidation of biological substrates by chromium(VI). Part 1. Mechanism of the oxidation of L-ascorbic acid in aqueous solution

Acrylamide in Caribbean foods – Residual levels and their relation to reducing sugar and asparagine content

Mechanism of Nitric Oxide Release. I. Two-electron Reduction of Sodium Nitroprusside by l -cysteine in Aqueous Solution

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