With the rise of IoT botnets, the remediation of infected devices has become a critical task. As over 87% of these devices reside in broadband networks, this task will fall primarily to consumers and the Internet Service Providers. We present the first empirical study of IoT malware cleanup in the wild-more specifically, of removing Mirai infections in the network of a medium-sized ISP. To measure remediation rates, we combine data from an observational study and a randomized controlled trial involving 220 consumers who suffered a Mirai infection together with data from honeypots and darknets. We find that quarantining and notifying infected customers via a walled garden, a best practice from ISP botnet mitigation for conventional malware, remediates 92% of the infections within 14 days. Email-only notifications have no observable impact compared to a control group where no notifications were sent. We also measure surprisingly high natural remediation rates of 58-74% for this control group and for two reference networks where users were also not notified. Even more surprising, reinfection rates are low. Only 5% of the customers who remediated suffered another infection in the five months after our first study. This stands in contrast to our lab tests, which observed reinfection of real IoT devices within minutes-a discrepancy for which we explore various different possible explanations, but find no satisfactory answer. We gather data on customer experiences and actions via 76 phone interviews and the communications logs of the ISP. Remediation succeeds even though many users are operating from the wrong mental model-e.g., they run antivirus software on their PC to solve the infection of an IoT device. While quarantining infected devices is clearly highly effective, future work will have to resolve several remaining mysteries. Furthermore, it will be hard to scale up the walled garden solution because of the weak incentives of the ISPs.

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A novel method to synthesize 4-alkylpyrimidines by the mechanochemical magnesium-mediated Minisci reaction of pyrimidine derivatives and alkyl halides has been reported. The reaction process operates with a broad substrate scope and excellent regioselectivity under mild conditions with no requirement of transition-metal catalysts, solvents, and inert gas protection. The practicality of this protocol has been demonstrated by the up-scale synthesis, mechanochemical product derivatization, and antimalarial drug pyrimethamine preparation.

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