We collected and completely sequenced 28,469 full-length complementary DNA clones from Oryza sativa L. ssp. japonica cv. Nipponbare. Through homology searches of publicly available sequence data, we assigned tentative protein functions to 21,596 clones (75.86%). Mapping of the cDNA clones to genomic DNA revealed that there are 19,000 to 20,500 transcription units in the rice genome. Protein informatics analysis against the InterPro database revealed the existence of proteins presented in rice but not in Arabidopsis. Sixty-four percent of our cDNAs are homologous to Arabidopsis proteins.
We report measurements of low-temperature specific heat on the 4f 2 -based heavy-fermion superconductor PrOs 4 Sb 12 . In magnetic fields above 4.5 T in the normal state, distinct anomalies are found which demonstrate the existence of a field-induced ordered phase (FIOP). The Pr nuclear specific heat indicates an enhancement of the 4f magnetic moment in the FIOP. Utilizing a Maxwell relation, we conclude that anomalous entropy, which is expected for a single-site quadrupole Kondo model, is not concealed below 0.16 K in zero field. We also discuss two possible interpretations of the Schottky-like anomaly at $3 K, i.e., a crystalline-field excitation or a hybridization gap formation.The f -electron-related heavy fermion (HF) systems exhibiting superconductivity had previously been found only in Ce and U intermetallic compounds. Therefore, the recent observation of the first Pr-based heavy fermion superconductivity (HFSC) in a filled skutterudite PrOs 4 Sb 12 1) has profound scientific significance. The 4f 2 configuration of Pr ions in intermetallic compounds had been considered to be quite stable in view of there being no observation of strongly correlated electron behaviors until recent studies on PrInAg 2 2) and PrFe 4 P 12 , 3-5) in which this picture breaks down. In PrFe 4 P 12 , which is also a member of the filled skutterudites, we have shown by specific heat, 3) electrical resistivity 4) and de Haas-van Alphen (dHvA) effect measurements 5) that HF behaviors appear in high fields where a nonmagnetic ordered state, probably of quadrupole origin, is suppressed. To our knowledge, PrFe 4 P 12 is the only system for which such definitive evidence for the 4f 2 -based Fermi-liquid HF ground state has been obtained.Compelling evidence for the HFSC in PrOs 4 Sb 12 was given by a large specific heat jump ÁC=T ¼ 0:5 J/K 2 mol at T c ¼ 1:85 K on a pellet of compressed powdered single crystals. 1) The jump is superimposed on a Schottky-like anomaly appearing at $3 K. Bauer et al. 1) attributed this peak to a doublet-triplet (À 3 -À 5 in O h -type notation) crystalline-electric-field (CEF) thermal excitation, taking into account their magnetic susceptibility ðTÞ and inelastic neutron scattering data. Since the À 3 non-Kramers doublet ground state has quadrupole degrees of freedom, they pointed out the possibility that the HF behavior is associated with a quadrupolar Kondo effect 6) on the Pr-ion lattice. In order to confirm this scenario, it is essential to clarify how the entropy R ln 2 associated with the À 3 ground state is released and whether any residual entropy is hidden far below T c or not.In this letter, we report two important findings in PrOs 4 Sb 12 , based on specific heat and magnetization measurements on high-quality single crystalline samples:(1) clear evidence for the existence of a field-induced ordered phase (FIOP) and (2) confirmation that no anomalous entropy is concealed below 0.16 K in zero field.Single crystals of the filled skutterudite PrOs 4 Sb 12 and the reference compound LaOs 4 Sb 12 were gro...
Specific heat and magnetization measurements have been performed on high-quality single crystals of filled-skutterudite PrFe4P12 in order to study the high-field heavy fermion state (HFS) and low-field ordered state (ODS). From a broad hump observed in C/T vs T in HFS for magnetic fields applied along the 100 direction, the Kondo temperature of ∼ 9 K and the existence of ferromagnetic Pr-Pr interactions are deduced. The 141 Pr nuclear Schottky contribution, which works as a highly-sensitive on-site probe for the Pr magnetic moment, sets an upper bound for the ordered moment as ∼ 0.03µB /Pr-ion. This fact strongly indicates that the primary order parameter in the ODS is nonmagnetic and most probably of quadrupolar origin, combined with other experimental facts. Significantly suppressed heavy-fermion behavior in the ODS suggests a possibility that the quadrupolar degrees of freedom is essential for the heavy quasiparticle band formation in the HFS. Possible crystalline-electric-field level schemes estimated from the anisotropy in the magnetization are consistent with this conjecture. 71.27.+a, 75.40.Cx, 71.70.Jp, 71.70.Ch
We have measured both magnetoresistance and Hall effect in CeOs4Sb12 to clarify the large resistivity state ascribed to the Kondo insulating one and the origin of the phase transition near 0.9 K reported in the specific heat measurement. We found unusual temperature (T ) dependence both in the electrical resistivity ρ ∼ T −1/2 and the Hall coefficient RH ∼ T −1 over the wide temperature range of about two order of magnitude below ∼ 30 K, which can be explained as a combined effect of the temperature dependences of carrier density and carrier scattering by spin fluctuation. An anomaly related with the phase transition has been clearly observed in the transport properties, from which the H − T phase diagram is determined up to 14 T. Taking into account the small entropy change, the phase transition is most probably the spin density wave one. Both the electrical resistivity and Hall resistivity at 0.3 K is largely suppressed about an order of magnitude by magnetic fields above ∼ 3 T, suggesting a drastic change of electronic structure and a suppression of spin fluctuations under magnetic fields.
The magnetic properties and magnetocaloric effect (MCE) in the ternary intermetallic compound ErMn2Si2 have been studied by magnetization and heat capacity measurements. A giant reversible MCE has been observed, accompanied by a second order magnetic phase transition from paramagnetic to ferromagnetic at ∼4.5 K. Under a field change of 5 T, the maximum value of magnetic entropy change (−ΔSMmax) is 25.2 J kg−1 K−1 with no thermal and field hysteresis loss, and the corresponding maximum value of adiabatic temperature change (ΔTadmax) is 12.9 K. Particularly, the values of −ΔSMmax and ΔTadmax reached 20.0 J kg−1 K−1 and 5.4 K for a low field change of 2 T, respectively. The present results indicate that the ErMn2Si2 compound is an attractive candidate for low temperature magnetic refrigeration.
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