A nanopaper
sensor device that combines humidity sensing, wireless information
transmission, and degradability has been fabricated using wood-derived
nanopaper as the substrate and dielectric layers. The nanopaper shows
excellent suitability for capacitor dielectric layers because of its
high dielectric constant, insulating properties suitable for thin-film
formation, and lamination properties. A wireless transmission circuit
containing the nanopaper capacitor can transmit radio signals in the
megahertz band, and the relative humidity change can be output as
a change in the radio signal owing to the humidity sensitivity of
the nanopaper capacitor. More than 95% of the total volume of the
nanopaper sensor device decomposes in soil after 40 days. Because
the nanopaper sensor device does not need to be recovered, it is expected
to greatly contribute to a sustainable society through realization
of hyperdense observation networks by mass installation of sensor
devices.
Nanopaper prepared from holocellulose pulp is one of the best substrates for flexible electronics because of its high thermal resistance and high clear transparency. However, the clearness of nanopaper decreases with increasing concentration of the starting cellulose nanofiber dispersion—with the use of a 2.2 wt % dispersion, for example—resulting in translucent nanopaper with a high haze of 44%. To overcome this problem, we show that the dilution of this high-concentration dispersion with water followed by sonication for 10 s reduces the haze to less than 10% while maintaining the high thermal resistance of the nanopaper. Furthermore, the combination of water dilution and a short sonication treatment improves the clearness of the nanopaper, which would translate into cost savings for the transportation and storage of this highly concentrated cellulose nanofiber dispersion. Finally, we demonstrate the improvement of the electrical conductivity of clear transparent nanopaper prepared from an initially high-concentration dispersion by dropping and heating silver nanowire ink on the nanopaper. These achievements will pave the way toward the realization of the mass production of nanofiber-based flexible devices.
Abundant and renewable all-cellulose-derived humidity sensors are fabricated via direct laser writing of patterned electrodes onto TEMPO-oxidized cellulose fiber paper, offering versatile applicability for the “trillion sensor” era.
Recently, there has been remarkable progress in solar thermal heating by applying biomass-derived carbons, which can absorb and convert solar light into thermal energy. The design of subwavelength nanoporous and molecular structures of biomassderived carbons is required for suppressed reflection and enhanced absorption of solar light. However, such designs are difficult because conventional biomass-derived carbons exhibit intrinsic microstructures and are prepared under specific carbonization conditions. In this study, a wood cellulose nanofiber-derived carbon is proposed to tailor both subwavelength nanoporous and molecular structures. Cellulose nanofibers are first constructed into a paper, denoted as "nanopaper", exhibiting subwavelength nanoporous structures by tailoring the pore spaces between cellulose nanofibers. The as-prepared nanopaper is then carbonized at various controlled temperatures to tailor the cellulose molecular structure, i.e., grow graphitic carbon domains. The graphitic carbon domains grown by semicarbonization at 500 °C adequately balance solar absorption and reflection, while the subwavelength nanoporous structures suppress solar reflection. Thus, the semicarbonized nanopaper with tailored nanoporous and molecular structures exhibits superior solar thermal heating to competitive nanocarbons, also affording thermoelectric power generation. This study can guide the structural and functional design of bionanocarbons for solar thermal heating.
The orientation control and the formation of hierarchical structures of nanoscale components, such as bionanofibers and nanosheets, have attracted considerable research interest with the aim of achieving sophisticated functional materials. Herein, we report a simple and flexible strategy for constructing sophisticated hierarchical structures through electrophoretic and electrochemical deposition. Cellulose nanofibers (CNFs), which are used as model materials, are deposited on an anode in an aqueous dispersion and seamlessly oriented from horizontal to vertical relatively to the electrode by adjusting the applied voltage between the electrodes. The oriented CNF hydrogels not only exhibit anisotropic mechanical properties but also form complex orientations and hierarchical structures, such as cartilage-and plant stem-like configurations in response to electrode shape and applied voltage. This simple and flexible technique is expected to be applicable to various materials and contribute to a wide range of fields that include biomimicry, functional nanomaterials, and sustainable and functional moldings.
Water is detrimental to electronic
devices because it easily causes
short circuits. The use of sealing to prevent water permeation is
considered as the current conventional solution; however, the trend
for developing flexible and stretchable electronic circuits has placed
severe demands on waterproof technologies. This report describes a
coating that protects circuits and prevents between-wire short circuits,
even if the waterproof seals are damaged and the circuit becomes wet.
We show that when Cu electrodes are coated with cellulose nanofibers
(carboxylate content of 1.8 mmol/g), short circuits between the electrodes
do not occur, even if the circuit is submerged in water for 24 h.
The cellulose nanofibers accumulate at the anode because of electrophoresis,
thereby forming a cohesive cellulose nanofiber layer that prevents
short circuits between electrodes. Even if the cellulose nanofiber
coating cracks because of external factors, the electrophoretic effect
repairs the coating. This failure-containment mechanism is expected
to be used in combination with existing waterproofing technology to
dramatically improve the reliability of next-generation electronic
devices under extreme operating conditions.
Cellulose nanopapers fabricated by drying aqueous colloidal suspensions of cellulose nanofibers (CNFs) have characteristic hierarchic structures, which cause the problem that their optical properties, including their transparency or haze, vary due to the drying processes affecting CNF alignment. It is unclear when and how the colloidal CNFs align in the evaporation–condensation process from the randomly dispersed suspension to form the nanopaper. In this study, we found that the CNFs undergo a self-alignment sequence during the evaporation–condensation process to form chiral nematic nanopaper by observing the birefringence of the drying suspensions from both the top and side for two suspensions with different initial CNF concentrations. The layer structures of the CNFs first form on the surface by condensation of the suspension, owing to water evaporation from the surface. The thickness of the layered structure then increases and the CNFs begin to align within each layer plane, finally forming chiral nematic structures. A birefringence difference also occurs for dried nanopapers with similar transparency or haze because of the initial CNF concentration.
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