In terms of health, dyes have carcinogenic, mutagenic and toxic properties and can have adverse effects on health and the environment. Therefore, sewage containing to dyes must be purified before being discharged into the environment. The current study aimed to investigate the effectiveness of
Alcea rosea
root extract in Disperse red 60 and Reactive blue 19 dyes removal from synthetic sewage. In this study, the effect of different indices including pH (5–11),
Alcea rosea
concentration (50–300 mg/L) and initial dye concentration (10–80 mg/L) was investigated. During the tests, the coagulant was stirred with rapid mixing at a speed of 250 rpm for 2 min. In the following, the speed (30–60 rpm) and the time (10–25 min) were used for slow mixing and after mixing the effect of settling time (10–60 min) and temperature (20–70) on removal efficiency of Disperse and Reactive dyes was investigated. The results showed that the maximum of removal efficiency of Disperse and Reactive dyes in optimum conditions including (pH = 11, coagulant concentration = 200 and 250 mg/L, dye concentration 40 and 20 mg/L, speed 60 rpm, during 15 min with settling time 60 min and temperature 60 °C obtained 86% and 68%, respectively. According to the result, the
Alcea rosea
coagulant has the best ability in removing dyes from aqueous solutions and sewage, especially Disperse dyes. Disperse dye is much eliminated in the coagulation process due to its lower solubility, higher suspending materials and less required solved chemical oxygen demand to the total chemical oxygen demand (SCOD/TCOD).
Background and Objectives: Wastewater treatment of paper recycling and cardboard industries with the aim of water recycling and reducing environmental impact is one of the daily needs of industries. Therefore, the aim of the present study was to optimize the conditions of coagulation and flocculation process in wastewater treatment of paper recycling industries using the response surface method.
Materials and Methods:In this laboratory study, response surface method and central composite design were used to design the experiments and to determine the effects of the studied variables (pH, concentrations of alum, Poly aluminum chloride (PAC), and cationic polymer) on the total suspended solid (TSS) and chemical oxygen demand (COD) removal efficiency. Data analysis was done using ANOVA statistical test with a significant level of 0.05.
Results:The results showed that in the combination of PAC with cationic polymer (optimal conditions; pH=7.5, PAC concentration=450 mg/L, cationic polymer concentration=1.5 mg/L), the TSS and COD removal efficiency were 97.34% and 75.76%, respectively. In combination of alum with cationic polymer (optimal conditions; pH=8.5, alum concentration=550 mg/L, cationic polymer concentration=2 mg/L), removal efficiencies were 98.96% and 77.83%, respectively. The simultaneous effects of two independent variables, pH and concentration, had a significant effect (p<0.05) in removing TSS and COD variables.
Conclusion:The results showed that the combination of PAC with cationic polymer had a better efficiency. Also, the COD and TSS in the final effluent were higher and lower than the standard values, respectively. Therefore, chemical coagulation process is proposed as pretreatment.
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