Polyimide‐based covalent organic frameworks (COFs) were synthesized via a geomimetic hydrothermal reaction, yielding materials with various pore dimensions and crystal structures, as described in the Research Article (e202113780) by Byeong‐Su Kim and co‐workers. The solubility of the oligomeric intermediates under hydrothermal conditions affected the growth mechanism and reaction pathway, which determined the 3D stacking structures of the polyimide‐based COFs.
As the demand for next-generation electronics is increasing, organic and polymer-based semiconductors are in the spotlight as suitable materials owing to their tailorable structures along with flexible properties. Especially, polyimide...
Kovalent‐organische Gerüste (COFs) auf Polyimidbasis wurden im Forschungsartikel (e202113780) von Byeong‐Su Kim et al. über eine geomimetische hydrothermale Reaktion synthetisiert, die Materialien mit unterschiedlichen Porendimensionen und Kristallstrukturen lieferte. Die Löslichkeit der oligomeren Zwischenprodukte unter hydrothermalen Bedingungen beeinflusste den Wachstumsmechanismus und den Reaktionsweg und damit die 3D‐Stapelstrukturen der Polyimid‐COFs.
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