Using a newly developed ultraclean electron cyclotron resonance plasma etcher, Si wafers masked by SiO2 were etched with a chlorine plasma at pressures of 0.6–4.0 mTorr with a microwave power of 300–700 W. Ultraclean processing under a low ion energy condition at high pressures has revealed that there is an induction period during which time there is no SiO2 etching. This is not observed with Si. During the induction period, perfectly selective etching for Si to SiO2 has been achieved. Under this perfectly selective condition, anisotropic tenth micron patterns of polycrystalline silicon have been obtained with little undercut.
B-1-1 hish anisotropy, and a cathodeless discharge f or low contamination .4 ,5) U* ing these properties, directional etching of Si with infinite selectlvity to Si02 has been realized with an ultraclean chlorine plasna. Using wafer voltage measurenents, the etching end-point could be deternined precisely.
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