The seasonal variations of the chemical budget of ions were determined from the hydrochemical investigation of the groundwater. Though the effect of monsoon does not change the order of abundance of cations, but it does change the concentration of various ions and it is found that there was a considerable change in the case of all major ions. The unique characteristic of the ground water is the linear relationship among the principal ions. Hydrochemical characteristics of ions in the groundwater were studied using 1:1 equiline diagrams. The nature of the water samples were determined using the piper diagram. The correlation studies and R-mode factor analysis were carried out on the various groundwater parameters. The study of factor scores reveals the extent of influence of each factors on the overall water chemistry at each sampling stations. The trace metal concentration in the water was determined. The quality of the groundwater in the study area has been assessed using Percent sodium, SAR and Wilcox diagrams. The groundwater results of the premonsoon shows the dominance of excessive evaporation, silicate weathering and anthropogenic activities whereas in postmonsoon, dilution predominates over that of other factors.

Multivariate statistical techniques were applied to identify and assess the quality of river water. Thirty samples were collected from the River Cooum, and basic chemical parameters--such as pH, effect concentration, total dissolved solids, major cations, anions, nutrients, and trace metals--were evaluated. To evaluate chemical variation and seasonal effect on the variables, analysis of variance and box-and-whisker plots were performed. Cluster analysis was applied, and pre-monsoon and post-monsoon major and minor clusters were classified. The relations among the stations were highlighted by cluster analysis, which were represented by dendograms to categorize different levels of contamination. Cluster analysis clearly grouped stations into polluted and unpolluted regions. The analysis classified the upper part of the river course into one unpolluted cluster; the middle and lower parts of the river clustered together, reflecting the presence of pollution. Factor analysis revealed that water quality is strongly affected by anthropogenic activities, rock-water interaction, and saline water intrusion. Seasonal variations in water chemistry were clearly highlighted by both cluster and factor analysis. Factor-score diagrams were used successfully to delineate the stations under study by the contributing factors, and seasonal effects on the sample stations were identified and evaluated. These statistical approaches and results yielded useful information about water quality and can lead to better water resource management.

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The River Adyar flows through the fault of south Chennai for about 50 Km and enters into the Bay of Bengal. This river is almost stagnant and do not carry enough water except during rainy season. Rapid industrialization and urbanization along the river course during 80s and 90s of last century has increased the pollution of the river water. The main objective of this study is to identify and assess the nature of pollution. In order to achieve this objective, necessary geochemical parameters were determined and the quality of water is evaluated using various tools, such as Wilcox diagram, USIS, Piper, sodium absorption ratio (SAR), 3D scattered diagrams, and seasonal variation diagrams. The monsoonal variations in the data matrix of the river water (River Adyar) was monitored at 33 stations for the premonsoon and postmonsoon periods during September 2005 and February 2006.

Hydrochemical investigations of the groundwater and the seasonal effect on the chemical budget of ions along the course of the polluted river Adyar were carried out. From the geochemical results, it has been found that the seasonal effect does not change the order of abundance of both cations and anions, but it does change the concentration of various ions present in the groundwater. Among the chemical budget of ions, sodium and chloride were found to be the most predominant ions. The nitrate concentration in the groundwater ranges from 4.21 to 45.93 mg/l in pre-monsoon and in post-monsoon it ranges from 1.02 to 75.91 mg/l. The nitrate concentrations in the post-monsoon are high in some places especially in the upper stretch of the river. The intense agricultural activities near the upper stretch of the river may be an important factor for the higher concentration of nitrates in these aquifers. In order to determine the geochemical nature of water, the data was interpreted using the piper diagram wherein the results show the predominance of NaCl and CaMgCl types. Equiline diagrams, 1:1, were applied to evaluate the affinity ion relationship between various ions present in these waters. The quality of the groundwater was assessed with regard to its suitability to drinking and irrigation. A comparison of the groundwater quality in relation to drinking water quality standards shows that most of the water samples are not suitable for drinking, especially in post-monsoon period. US Salinity Laboratory's, Wilcox's diagrams, Kellys ratio and magnesium ratio were used for evaluating the water quality for irrigation which suggest that the majority of the groundwater samples are not good for irrigation in post-monsoon compared to that in pre-monsoon. Moreover the source of the ions in the water was examined and classified accordingly using Gibb's diagram. The analytical results reveals that the TDS values of the pre-monsoon samples were found to be lower than the post-monsoon reflecting that leaching predominates over that of the dilution factor.

Peninsular India is an amalgam of transient landscapes evolved from the interactions between tectonic and climatic forcings. In order to appraise the tectono‐geomorphic evolution of South India, it is essential to understand the relationships between intrinsic and extrinsic processes and their geomorphic expressions at a river basin scale. Seven geomorphometric parameters, namely, longitudinal profile (Lp), asymmetry factor (Af), hypsometric curve and hypsometric integral (HI), mountain front sinuosity (Smf), river sinuosity (R), stream length gradient (Sl), and shape factor (Shp) were calculated for selected drainage basins of South India. Spatial analyses of these parameters in the light of systematic field mapping were attempted in this study. The results show the occurrences of southern sub‐basins with convex hypsometric curves indicating a youth stage and significant tectonic influence. The low and moderate Smf values within the basins are indicative of mountain fronts witnessing a high level of tectonic activity. The net effects of tectonic and geomorphometric processes are inferred to have been the responses of anti‐clockwise rotation of the Indian Plate and ridge uplift‐push from west. Directional change in Thamirabarani River Basin and drainage channel reorganizations in the Cauvery and Vaigai River basins stand testimony to these, among others. Amidst these, occurrences of tectonically quiescent regions and multiple incisions by river channels and flow of modern river channels in inherited palaeovalleys but on tangent directions of ancient flows are also observed. Five stages of landscape development are envisaged: First, inheritance of river basins from palaeodrainage systems; second, reversal of river flow directions during early part of Cenozoic and inception of evolution of modern river systems; third, during Miocene–Pliocene; fourth, during Pleistocene–Early Holocene; and fifth, during the Holocene–Anthropocene. The recent resurgence of tectonics is not only reflected in the shifting of axial rivers, but is also evidenced by seismicity and landslides/faulting. Together, transient nature of the Southern Indian Plate, first‐order control of tectonics, followed by climate and lithology over landscape evolution, inheritance of river valleys, synonymy of river basin responses to intrinsic and extrinsic geomorphic processes, however with unique signatures and basin‐scale responses, are inferred. Detailed morphometric studies and supplementation with precise age data may fine‐tune the proposed model. According to the model, inheritance of Mesozoic valley/structures during Late Jurassic–Early Cretaceous, drainage reversal and initiation of Cenozoic–Recent river basin evolution, intense peneplanation during Miocene–Pliocene, intense incision during Pleistocene, periodic climatic extremes during Early Cenozoic, Palaeocene–Eocene, Oligocene and corresponding pedogenesis, and terrace formation and sedimentation have been recognized. Based on the numerical ages and documentation of basin‐scale distribution of s...

The salient features of the river water chemistry and the seasonal variations on the individual chemical parameter were evaluated and characterized. The order of abundance of the ions in the water is determined for both seasons. The contribution of chemical weathering to the water chemistry has been determined using the (Ca(2+) + Mg(2+))/(Na(+) + K(+)) ratio, ternary, and Gibb's diagrams. The results show that the chemical composition of river water during premonsoon is controlled mainly by evaporation-crystallization, while in the postmonsoon, the rock-water interaction dominates. The unique characteristic of the river water is the linear relationship among the principal ions. Hydrochemical characteristics of ions in the water were studied using 1:1 equiline diagrams. The nature of the water samples was determined using the piper diagram. The influence of trace metals on the chemical composition and the quality of the river water in the study area has been assessed using Wilcox and US Salinity Laboratory diagrams.