Large septarian concretions from the Kimmeridge Clay, up to 1.2 m in diameter, have centres comprising anhedral calcite microspar passing into margins of radiating fibrous calcite microspar, with a pyrite‐rich zone at the transition. Septarian veins formed and were lined with brown calcite synchronously with fibrous matrix growth, with white calcite precipitated in septarian cavities after concretion growth ceased. Septarian veins, filled only with white calcite, formed later, at the same time as the outermost calcite microspar crystals were enlarged. The concretions were buried in the Late Jurassic to about 130 m, and in the Late Cretaceous to about 550 m, with uplift between. Oxygen isotopes show that the concretion grew throughout the first burial, with septarian veins forming from about 30 m depth onwards. Later septarian veins formed between about 200 and 500 m during the second burial. Carbon isotopes show that the compact inner matrix grew in the sulphate reduction zone, the end of which is marked by the pyrite‐enriched zone. Dissolving shells, and possibly minor methanogenic carbonate, slowly diluted sulphate reduction‐zone carbonate during deeper burial. During early concretion growth, Mg and Sr were depleted in the pore water. During later stages of the first burial, Mg, Sr, Mn and Fe all increased, especially after concretion growth ceased. During the second burial, Fe, Mn and Mg decreased as calcite precipitated, implying relatively closed systems for these elements. Synchronous formation of septarian fractures and fibrous calcite matrix shows that the Kimmeridge Clay became overpressured during the later stages of both burials.
The textural evidence in septarian concretions shows that the septa formed as tensile fractures during burial and compaction of the host shale. Comparison of the combinations of vertical and horizontal stresses and pore-fluid pressure required for tensile fracture of cemented concretions and those likely to occur during shale burial indicates that septarian fracturing will be favoured by overpressuring and low horizontal stress, most likely to occur during times of rapid burial. Burial histories of septarian concretions from the Eocene London Clay and the Jurassic Kimmeridge Clay show that fracturing can form under as little as 50 m of sediment. By relating episodes of septarian fracturing to times of rapid burial, the timing of diagenetic cement formation can be constrained.
The influences of tectonic and climatic changes on upland river systems are investigated using data from Plio-Pleistocene terraces of the Rio Cinca river in the southern Pyrenees. This river runs transverse to the main thrust fault structures and is a major conduit for sediment delivery to the Ebro Basin. Detailed field mapping, combined with long-profile and palaeohydraulic reconstructions, yields a comprehensive picture of changes in palaeoriver character during the Plio-Pleistocene. As the area is over 150 km from the basin outlet in the Mediterranean Sea, changes in base level are unlikely to have influenced terrace development. Although tectonic activity has exerted a strong control on the position of the river, the main period of thrust propagation pre-dates the terraces and activity has waned from the Pliocene through to the present. It is concluded that the main control on incision in this area is climate, through its influence on sediment supply. Rivers which are starved of sediment by climate change will have the power to incise, whereas aggradational phases are linked to periods of increased sediment flux.
The Late Devonian early tetrapods in East Greenland occur in the Celsius Bjerg Group. Key occurrences are located in a detailed stratigraphic section used here to interpret the sedimentary palaeoenvironments. The palaeoenvironment for the Britta Dal Formation (which contains both Ichthyostega and Acanthostega) is reinterpreted. The Britta Dal Formation channels have flat bases, are poorly channelized, are of low sinuosity and are part of a very major distributory system that periodically experienced extreme flooding. The tetrapod fossils were recovered from an ephemeral system that was not permanently habitable in the immediate area. Plant megafossils are poorly preserved casts and impressions dominated by lycopsids and fern-like plants. The overbank siltstones are dominated by arid soil forming processes and comprise a spectacular sequence of vertisols. The 1174 m in situ Ichthyostega locality in Paralleldal was relocated and occurs just below the midpoint of the second megacycle in the Britta Dal Formation.
There is significant evidence that the anelastic loss of seismic energy is linked to petrophysical properties such as porosity, permeability and clay content. Thus, reliable estimation of anelastic attenuation from seismic data can lead to improved methods for the prediction of petrophysical properties. This paper is concerned with methods for the estimation of attenuation at sonic frequencies (5–30 KHz) from in situ data. Two independent methods have been developed and tested for estimating compressional‐wave attenuation from full‐waveform sonic data. A well‐established technique, the logarithm spectral ratio (LSR) method, is compared with a new technique, the instantaneous frequency (IF) method. The LSR method uses the whole spectrum of the seismic pulse whilst the IF method uses a carefully estimated value of instantaneous frequency which is representative of the centre frequency of the pulse. In the former case, attenuation estimation is based on the relative variation of amplitudes at different frequencies, whilst in the latter case it is based on the shift of the centre frequency of the pulse to lower values during anelastic wave propagation. The IF method does not assume frequency independence of Q which is a necessary assumption for the LSR method, and it provides a stable frequency log, the peak instantaneous frequency (PIF) log, which may be used as an indicator for attenuation under certain limitations. The development and implementation of the two methods is aimed at minimizing the effect of secondary arrivals, such as leaky modes, and involved a series of parameter tests. Testing of the two methods using full‐waveform sonic data of variable quality, obtained from a gas‐bearing sandstone reservoir, showed that the IF method is in general more stable and suitable for full‐waveform sonic data compared with the LSR method. This was evident especially in data sets with high background noise levels and wave‐interference effects. For good quality data, the two methods gave results that showed good agreement, whilst comparison with other log types further increased confidence in the results obtained. A significant decrease (approximately 5 KHz) in the PIF values was observed in the transition from an evaporite/shale sequence to the gas‐bearing sandstone. Average Q values of 54 and 51 were obtained using good quality data from a test region within the gas‐saturated sandstone reservoir, using the LSR and IF methods, respectively.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.
hi@scite.ai
10624 S. Eastern Ave., Ste. A-614
Henderson, NV 89052, USA
Copyright © 2024 scite LLC. All rights reserved.
Made with 💙 for researchers
Part of the Research Solutions Family.