Die Besonderheiten des Ablaufs der radikalischen Polymerisation einiger Acrylmonomere in Gegenwart von hochdispersen aktiven Fullstoffen -Aerosil und Polyvinylchlorid-Pulverwerden unter Beriicksichtigung elementarer Reaktionen analysiert. Insbesondere werden die Reaktionskinetik und der Mechanismus der Startreaktion untersucht. Der EinfluB des Fullstoffs auf die physikalisch-mechanischcn und physikalisch-chemischen Eigenschaften der Polymere wird diskutiert. llonuncepuaayu~ Monoaepos axpmoeozo p s d a 8 npucymcrnsuu amnusnwx nanomurneneii Boro pnna B IIPACJ'TCTBHH BbIcoKoAHcnepcHbIx a K T m H b I x HanonHwreneia s p o c~n a A nopoluKa IIOJIHBHHHJIXJIO-acnexiToB II ~e x a~m~y npoTeKaHm peaKqmi m a q m p o R a H m . PaccMoTpeHo TaKme B n m m e HanonHmenn H a @ A~H K O -M~X~H A~~C K H~ A @ A~H K O -X H M H Y~C K H~ cRoicTsa nonnMepoB. The polymerization of acrylic monomers in the presence of active fillersThe pecularities of the radical polymerization of some acrylic monomers in the presence of highly disperse fillers, as aerosil and poly(viny1 chloride) powder, were investigated with respect to the basic reactions. Particularly, the kinetics and mechanism of initiation were considered. The effects of fillers on the physical and chemical properties of the B AaHHOa p a 6 o~e aHaJlA3ApJ'lOTCfl OCO6eHHOCTA npOTeKaHEiR p~AKanbHOfi nOJlAMepH3a~HH MOHOMePOB aKpHJI0-PAna (nBx) C YqeTOM WIeMeHTapHbIX PeaKQafi. Oco6oe BHHMaHHe J',W?JIeHO PaCCMOTpeHHIO KHHeTH9eCKHX polymers are discussed.
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